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@ARTICLE{VelazquezGarcia:622232,
      author       = {Velazquez Garcia, Jose and Del los Santos Valladares, Luis
                      and Barnes, Crispin H. W. and König, Sandra and Froeba,
                      Michael and Baran, Volodymyr and Knjo, Bassima and
                      Khademhir, Faegheh and Ekineken, Aliyenur and Hain, Fabienne
                      and Carstensen, Evke and Spillner, Tom and Asprilla Herrera,
                      Lina Maria and Lukaszczyk, Weronika and Techert, Simone},
      title        = {{N}eutral and {I}onic {C}o({II}) {M}etal-{O}rganic
                      {F}rameworks with 2-{M}ethylimidazole and {T}rimesate:
                      {D}esign and {E}valuation for {M}olecule {E}ncapsulation and
                      {S}low {R}elease},
      journal      = {Dalton transactions},
      volume       = {54},
      issn         = {0300-9246},
      address      = {London},
      publisher    = {Soc.},
      reportid     = {PUBDB-2025-00270},
      pages        = {4449 - 4460},
      year         = {2025},
      abstract     = {Two Co(II) mixed-ligand metal-organic frameworks (MOFs)
                      based on 2-methylimidazole and trimesate were synthesised at
                      room temperature. The structure and properties of the two
                      MOFs, named material Deutsches Elektronen Synchrotron-1 and
                      -2 (mDESY-1 and mDESY-2), were verified by single crystal
                      X-ray diffraction (SCXRD), powder X-ray diffraction (PXRD),
                      SQUID magnetic susceptibility and N2 adsorption. The
                      structural analysis indicates that mDESY-1 is a 3D ionic
                      framework with 2-methyl-1H-imidazol-3-ium counterions
                      residing in its pores, while mDESY-2 is a 2D neutral
                      framework isostructural to ITH-1, with water as a
                      co-crystallising solvent. PXRD data demonstrates that
                      mDESY-1 exhibits better crystallinity than mDESY-2. Magnetic
                      measurements indicate that both MOFs are paramagnetic with a
                      weak ferromagnetic transition above room temperature.
                      Although both structures suggest the presence of voids, N2
                      adsorption data confirms that these voids are not accessible
                      in either MOF. Nevertheless, mDESY-1 was capable of
                      encapsulating azobenzene during synthesis, which was
                      observed via SCXRD. The encapsulated molecules were then
                      slowly released in ethanol, with a release of up to 30mg of
                      azobenzene per g of MOF in a period of 60 days.},
      cin          = {FS-SCS},
      ddc          = {540},
      cid          = {I:(DE-H253)FS-SCS-20131031},
      pnm          = {632 - Materials – Quantum, Complex and Functional
                      Materials (POF4-632) / 6G3 - PETRA III (DESY) (POF4-6G3) /
                      DFG project G:(GEPRIS)217133147 - SFB 1073: Kontrolle von
                      Energiewandlung auf atomaren Skalen (217133147) / SFB 1073
                      B06 - Echtzeituntersuchungen der optischen Anregung in
                      oligonuklearen Metallkomplexen mit schaltbaren Spin- und
                      Ladungszuständen (B06) (240171831)},
      pid          = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G3 /
                      G:(GEPRIS)217133147 / G:(GEPRIS)240171831},
      experiment   = {EXP:(DE-H253)P-P11-20150101 /
                      EXP:(DE-H253)P-P02.1-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:39812590},
      UT           = {WOS:001398581300001},
      doi          = {10.1039/D4DT02679A},
      url          = {https://bib-pubdb1.desy.de/record/622232},
}