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@ARTICLE{Richard:622139,
author = {Richard, Benoit and Boll, Rebecca and Banerjee, Sourav and
Schaefer, Julia and Jurek, Zoltan and Kastirke, Gregor and
Fehre, Kilian and Schoeffler, Markus and Anders, Nils and
Baumann, Thomas and Eckart, Sebastian and Erk, Benjamin and
De Fanis, Alberto and Doerner, Reinhard and Grundmann, Sven
and Grychtol, Patrik and Hofmann, Max and Ilchen, Markus and
Kircher, Max and Kubicek, Katharina and Kunitski, Maxim and
Li, Xiang and Mazza, Tommaso and Meister, Severin and
Melzer, Niklas and Montano, Jacobo and Music, Valerija and
Ovcharenko, Yevheniy and Passow, Christopher and Pier,
Andreas and Rennhack, Nils and Rist, Jonas and Rivas, Daniel
and Rolles, Daniel and Schlichting, Ilme and Schmidt, Lothar
and Schmidt, Philipp and Trabert, Daniel and Trinter,
Florian and Wagner, Rene and Walter, Peter and Ziolkowski,
Pawel and Rudenko, Artem and Meyer, Michael and Santra,
Robin and Inhester, Ludger and Jahnke, Till},
title = {{I}maging collective quantum fluctuations of the structure
of acomplex molecule},
journal = {Science / Science now},
volume = {389},
number = {6760},
issn = {0036-8075},
address = {Washington, DC},
publisher = {Assoc.},
reportid = {PUBDB-2025-00204},
pages = {650 - 654},
year = {2025},
note = {ISSN 1095-9203 not unique: **3 hits**.},
abstract = {Because of the Heisenberg uncertainty principle, the
structure of a molecule fluctuates about its mean geometry,
even in the ground state. Observing this fundamental quantum
effect experimentally—particularly, revealing the
collective nature of the structural quantum
fluctuations—remains an unmet challenge for complex
molecules. In this work, we achieved this for an 11-atom
molecule by inducing its Coulomb explosion with an x-ray
free-electron laser. We show that the structural
fluctuations manifest themselves in correlated variations of
ion momenta obtained through coincident detection of the
atomic fragments from individual molecules. Our analysis
scheme allows extracting these variations, despite our
measurements covering only a fraction of the full
33-dimensional momentum space, thereby establishing a
general approach for extracting information on
high-dimensional structural dynamics using Coulomb
explosion.},
cin = {FS-CFEL-3 / CFEL-DESYT},
ddc = {320},
cid = {I:(DE-H253)FS-CFEL-3-20120731 /
I:(DE-H253)CFEL-DESYT-20160930},
pnm = {631 - Matter – Dynamics, Mechanisms and Control
(POF4-631) / AIM, DFG project G:(GEPRIS)390715994 - EXC
2056: CUI: Advanced Imaging of Matter (390715994) / DFG
project G:(GEPRIS)509471550 - Dynamik
photoionisations-induzierter Prozesse in laser-präparierten
Molekülen in der Gasphase und der wässrigen Phase
(509471550) / DFG project G:(GEPRIS)497431350 - Funktionale
Photoschalter bei Zimmertemperatur: Fernsteuerung
metallischer elektronischer und Spinänderungen mittels
Ligandendynamik (497431350)},
pid = {G:(DE-HGF)POF4-631 / G:(GEPRIS)390715994 /
G:(GEPRIS)509471550 / G:(GEPRIS)497431350},
experiment = {EXP:(DE-H253)XFEL-SQS-20150101},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:40773565},
doi = {10.1126/science.adu2637},
url = {https://bib-pubdb1.desy.de/record/622139},
}