TY - JOUR
AU - Richard, Benoit
AU - Boll, Rebecca
AU - Banerjee, Sourav
AU - Schaefer, Julia
AU - Jurek, Zoltan
AU - Kastirke, Gregor
AU - Fehre, Kilian
AU - Schoeffler, Markus
AU - Anders, Nils
AU - Baumann, Thomas
AU - Eckart, Sebastian
AU - Erk, Benjamin
AU - De Fanis, Alberto
AU - Doerner, Reinhard
AU - Grundmann, Sven
AU - Grychtol, Patrik
AU - Hofmann, Max
AU - Ilchen, Markus
AU - Kircher, Max
AU - Kubicek, Katharina
AU - Kunitski, Maxim
AU - Li, Xiang
AU - Mazza, Tommaso
AU - Meister, Severin
AU - Melzer, Niklas
AU - Montano, Jacobo
AU - Music, Valerija
AU - Ovcharenko, Yevheniy
AU - Passow, Christopher
AU - Pier, Andreas
AU - Rennhack, Nils
AU - Rist, Jonas
AU - Rivas, Daniel
AU - Rolles, Daniel
AU - Schlichting, Ilme
AU - Schmidt, Lothar
AU - Schmidt, Philipp
AU - Trabert, Daniel
AU - Trinter, Florian
AU - Wagner, Rene
AU - Walter, Peter
AU - Ziolkowski, Pawel
AU - Rudenko, Artem
AU - Meyer, Michael
AU - Santra, Robin
AU - Inhester, Ludger
AU - Jahnke, Till
TI - Imaging collective quantum fluctuations of the structure of acomplex molecule
JO - Science / Science now
VL - 389
IS - 6760
SN - 0036-8075
CY - Washington, DC
PB - Assoc.
M1 - PUBDB-2025-00204
SP - 650 - 654
PY - 2025
N1 - ISSN 1095-9203 not unique: **3 hits**.
AB - Because of the Heisenberg uncertainty principle, the structure of a molecule fluctuates about its mean geometry, even in the ground state. Observing this fundamental quantum effect experimentally—particularly, revealing the collective nature of the structural quantum fluctuations—remains an unmet challenge for complex molecules. In this work, we achieved this for an 11-atom molecule by inducing its Coulomb explosion with an x-ray free-electron laser. We show that the structural fluctuations manifest themselves in correlated variations of ion momenta obtained through coincident detection of the atomic fragments from individual molecules. Our analysis scheme allows extracting these variations, despite our measurements covering only a fraction of the full 33-dimensional momentum space, thereby establishing a general approach for extracting information on high-dimensional structural dynamics using Coulomb explosion.
LB - PUB:(DE-HGF)16
C6 - pmid:40773565
DO - DOI:10.1126/science.adu2637
UR - https://bib-pubdb1.desy.de/record/622139
ER -