% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Aleksich:620206,
      author       = {Aleksich, Mariya and Cho, Yeongsu and Paley, Daniel W. and
                      Willson, Maggie C. and Nyiera, Hawi N. and Kotei, Patience
                      A. and Oklejas, Vanessa and Mittan-Moreau, David W. and
                      Schriber, Elyse A. and Christensen, Kara and Inoue, Ichiro
                      and Owada, Shigeki and Tono, Kensuke and Sugahara, Michihiro
                      and Inaba-Inoue, Satomi and Vakili, Mohammad and Milne,
                      Christopher J. and DallAntonia, Fabio and Khakhulin, Dmitry
                      and Ardana-Lamas, Fernando and Lima, Frederico and Valerio,
                      Joana and Han, Huijong and Gallo, Tamires and Yousef, Hazem
                      and Turkot, Oleksii and Macias, Ivette J. Bermudez and
                      Kluyver, Thomas and Schmidt, Philipp and Gelisio, Luca and
                      Round, Adam R. and Jiang, Yifeng and Vinci, Doriana and
                      Uemura, Yohei and Kloos, Marco and Mancuso, Adrian P. and
                      Warren, Mark and Sauter, Nicholas K. and Zhao, Jing and
                      Smidt, Tess and Kulik, Heather J. and Sharifzadeh, Sahar and
                      Brewster, Aaron S. and Hohman, J. Nathan},
      title        = {{L}igand‐{M}ediated {Q}uantum {Y}ield {E}nhancement in
                      1‐{D} {S}ilver {O}rganothiolate {M}etal–{O}rganic
                      {C}halcogenolates},
      journal      = {Advanced functional materials},
      volume       = {35},
      number       = {6},
      issn         = {1616-301X},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {PUBDB-2025-00079},
      pages        = {2414914},
      year         = {2025},
      note         = {waiting for fulltext},
      abstract     = {X-ray free electron laser (XFEL) microcrystallography and
                      synchrotron single-crystal crystallography are used to
                      evaluate the role of organic substituent position on the
                      optoelectronic properties of metal–organic chalcogenolates
                      (MOChas). MOChas are crystalline 1D and 2D semiconducting
                      hybrid materials that have varying optoelectronic properties
                      depending on composition, topology, and structure. While
                      MOChas have attracted much interest, small crystal sizes
                      impede routine crystal structure determination. A series of
                      constitutional isomers where the aryl thiol is
                      functionalized by either methoxy or methyl ester are solved
                      by small molecule serial femtosecond X-ray crystallography
                      (smSFX) and single crystal rotational crystallography. While
                      all the methoxy examples have a low quantum yield $(0-1\%),$
                      the methyl ester in the ortho position yields a high quantum
                      yield of $22\%.$ The proximity of the oxygen atoms to the
                      silver inorganic core correlates to a considerable
                      enhancement of quantum yield. Four crystal structures are
                      solved at a resolution range of 0.8–1.0 Å revealing a
                      collapse of the 2D topology for functional groups in the 2-
                      and 3- positions, resulting in needle-like crystals. Further
                      analysis using density functional theory (DFT) and many-body
                      perturbation theory (MBPT) enables the exploration of
                      complex excitonic phenomena within easily prepared material
                      systems.},
      cin          = {$XFEL_E1_SPB/SFX$ / FS-CFEL-1},
      ddc          = {530},
      cid          = {$I:(DE-H253)XFEL_E1_SPB_SFX-20210408$ /
                      I:(DE-H253)FS-CFEL-1-20120731},
      pnm          = {633 - Life Sciences – Building Blocks of Life: Structure
                      and Function (POF4-633)},
      pid          = {G:(DE-HGF)POF4-633},
      experiment   = {EXP:(DE-H253)XFEL-FXE-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:001367472900001},
      doi          = {10.1002/adfm.202414914},
      url          = {https://bib-pubdb1.desy.de/record/620206},
}