TY  - JOUR
AU  - Aleksich, Mariya
AU  - Cho, Yeongsu
AU  - Paley, Daniel W.
AU  - Willson, Maggie C.
AU  - Nyiera, Hawi N.
AU  - Kotei, Patience A.
AU  - Oklejas, Vanessa
AU  - Mittan-Moreau, David W.
AU  - Schriber, Elyse A.
AU  - Christensen, Kara
AU  - Inoue, Ichiro
AU  - Owada, Shigeki
AU  - Tono, Kensuke
AU  - Sugahara, Michihiro
AU  - Inaba-Inoue, Satomi
AU  - Vakili, Mohammad
AU  - Milne, Christopher J.
AU  - DallAntonia, Fabio
AU  - Khakhulin, Dmitry
AU  - Ardana-Lamas, Fernando
AU  - Lima, Frederico
AU  - Valerio, Joana
AU  - Han, Huijong
AU  - Gallo, Tamires
AU  - Yousef, Hazem
AU  - Turkot, Oleksii
AU  - Macias, Ivette J. Bermudez
AU  - Kluyver, Thomas
AU  - Schmidt, Philipp
AU  - Gelisio, Luca
AU  - Round, Adam R.
AU  - Jiang, Yifeng
AU  - Vinci, Doriana
AU  - Uemura, Yohei
AU  - Kloos, Marco
AU  - Mancuso, Adrian P.
AU  - Warren, Mark
AU  - Sauter, Nicholas K.
AU  - Zhao, Jing
AU  - Smidt, Tess
AU  - Kulik, Heather J.
AU  - Sharifzadeh, Sahar
AU  - Brewster, Aaron S.
AU  - Hohman, J. Nathan
TI  - Ligand‐Mediated Quantum Yield Enhancement in 1‐D Silver Organothiolate Metal–Organic Chalcogenolates
JO  - Advanced functional materials
VL  - 35
IS  - 6
SN  - 1616-301X
CY  - Weinheim
PB  - Wiley-VCH
M1  - PUBDB-2025-00079
SP  - 2414914
PY  - 2025
N1  - waiting for fulltext
AB  - X-ray free electron laser (XFEL) microcrystallography and synchrotron single-crystal crystallography are used to evaluate the role of organic substituent position on the optoelectronic properties of metal–organic chalcogenolates (MOChas). MOChas are crystalline 1D and 2D semiconducting hybrid materials that have varying optoelectronic properties depending on composition, topology, and structure. While MOChas have attracted much interest, small crystal sizes impede routine crystal structure determination. A series of constitutional isomers where the aryl thiol is functionalized by either methoxy or methyl ester are solved by small molecule serial femtosecond X-ray crystallography (smSFX) and single crystal rotational crystallography. While all the methoxy examples have a low quantum yield (0-1
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:001367472900001
DO  - DOI:10.1002/adfm.202414914
UR  - https://bib-pubdb1.desy.de/record/620206
ER  -