%0 Journal Article
%A Aleksich, Mariya
%A Cho, Yeongsu
%A Paley, Daniel W.
%A Willson, Maggie C.
%A Nyiera, Hawi N.
%A Kotei, Patience A.
%A Oklejas, Vanessa
%A Mittan-Moreau, David W.
%A Schriber, Elyse A.
%A Christensen, Kara
%A Inoue, Ichiro
%A Owada, Shigeki
%A Tono, Kensuke
%A Sugahara, Michihiro
%A Inaba-Inoue, Satomi
%A Vakili, Mohammad
%A Milne, Christopher J.
%A DallAntonia, Fabio
%A Khakhulin, Dmitry
%A Ardana-Lamas, Fernando
%A Lima, Frederico
%A Valerio, Joana
%A Han, Huijong
%A Gallo, Tamires
%A Yousef, Hazem
%A Turkot, Oleksii
%A Macias, Ivette J. Bermudez
%A Kluyver, Thomas
%A Schmidt, Philipp
%A Gelisio, Luca
%A Round, Adam R.
%A Jiang, Yifeng
%A Vinci, Doriana
%A Uemura, Yohei
%A Kloos, Marco
%A Mancuso, Adrian P.
%A Warren, Mark
%A Sauter, Nicholas K.
%A Zhao, Jing
%A Smidt, Tess
%A Kulik, Heather J.
%A Sharifzadeh, Sahar
%A Brewster, Aaron S.
%A Hohman, J. Nathan
%T Ligand‐Mediated Quantum Yield Enhancement in 1‐D Silver Organothiolate Metal–Organic Chalcogenolates
%J Advanced functional materials
%V 35
%N 6
%@ 1616-301X
%C Weinheim
%I Wiley-VCH
%M PUBDB-2025-00079
%P 2414914
%D 2025
%Z waiting for fulltext
%X X-ray free electron laser (XFEL) microcrystallography and synchrotron single-crystal crystallography are used to evaluate the role of organic substituent position on the optoelectronic properties of metal–organic chalcogenolates (MOChas). MOChas are crystalline 1D and 2D semiconducting hybrid materials that have varying optoelectronic properties depending on composition, topology, and structure. While MOChas have attracted much interest, small crystal sizes impede routine crystal structure determination. A series of constitutional isomers where the aryl thiol is functionalized by either methoxy or methyl ester are solved by small molecule serial femtosecond X-ray crystallography (smSFX) and single crystal rotational crystallography. While all the methoxy examples have a low quantum yield (0-1
%F PUB:(DE-HGF)16
%9 Journal Article
%U <Go to ISI:>//WOS:001367472900001
%R 10.1002/adfm.202414914
%U https://bib-pubdb1.desy.de/record/620206