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@ARTICLE{Mazalova:620198,
      author       = {Mazalova, Victoria and Asanova, Tatiana and Asanov, Igor
                      and Fromme, Petra},
      title        = {{A} {S}tructure and {M}agnetism {S}tudy of {{M}n$^{{II}}$$
                      _3${M}n$^{{IV}}${L}n$^{{III}}$$ _3$} {C}oordination
                      {C}omplexes with {L}n = {D}y, {Y}b},
      journal      = {Inorganics},
      volume       = {12},
      number       = {11},
      issn         = {2304-6740},
      address      = {Basel},
      publisher    = {MDPI},
      reportid     = {PUBDB-2025-00074},
      pages        = {286},
      year         = {2024},
      abstract     = {We report the research results of polynuclear complexes
                      consisting of 3d-4f mixed-metal cores that are maintained by
                      acetate ligands and multidentate Schiff base ligands with
                      structurally exposed thioether groups. The presence of the
                      latter at the periphery of these neutral compounds enables
                      their anchoring onto substrate surfaces. Specifically, we
                      investigated the electronic and magnetic properties as well
                      as the structural arrangement in
                      Mn$^{II}$$_3$Mn$^{IV}$Ln$^{III}$$_3$ with Ln = Dy, Yb
                      coordination complexes using various complementary methods.
                      We studied the electronic and atomic structure of the target
                      compounds using the XAS and XES techniques. The molecular
                      structures of the compounds were determined using density
                      functional theory, and the magnetic data were obtained as a
                      function of the magnetic field. Using the XMCD method, we
                      followed the changes in the electronic and magnetic
                      properties of adsorbed magnetic compounds induced by the
                      reaction of ligands through interaction with the substrate.
                      The complexes show antiferromagnetic exchange interactions
                      between Mn and Ln ions. The spectroscopic analyses confirmed
                      the structural and electronic integrity of complexes in
                      organic solution. This study provides important input for a
                      full understanding of the dependence of the magnetic
                      properties and the molecule–substrate interaction of
                      single adsorbed molecules on the type of ligands. It
                      highlights the importance of chemical synthesis for
                      controlling and tailoring the magnetic properties of
                      metalorganic molecules for their use as optimized building
                      blocks of future molecular spin electronics.},
      cin          = {FS-CFEL-1 / FS DOOR-User},
      ddc          = {540},
      cid          = {I:(DE-H253)FS-CFEL-1-20120731 /
                      $I:(DE-H253)FS_DOOR-User-20241023$},
      pnm          = {633 - Life Sciences – Building Blocks of Life: Structure
                      and Function (POF4-633) / 6G3 - PETRA III (DESY) (POF4-6G3)
                      / AXSIS - Frontiers in Attosecond X-ray Science: Imaging and
                      Spectroscopy (609920)},
      pid          = {G:(DE-HGF)POF4-633 / G:(DE-HGF)POF4-6G3 /
                      G:(EU-Grant)609920},
      experiment   = {EXP:(DE-H253)P-P64-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:001365464700001},
      doi          = {10.3390/inorganics12110286},
      url          = {https://bib-pubdb1.desy.de/record/620198},
}