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@ARTICLE{Hauko:620187,
author = {Hauko, R. and Gomilšek, J. Padežnik and Kodre, A. and
Arčon, I. and Luin, U.},
title = {{I}odine {K}- and {L}-edge {X}-ray absorption spectra of
{HI}: {T}he effect of molecular orbitals and core subshells},
journal = {Radiation physics and chemistry},
volume = {229},
issn = {0969-806X},
address = {Frankfurt, M.},
publisher = {Pergamon Press},
reportid = {PUBDB-2025-00065},
pages = {112509},
year = {2025},
note = {ISSN 0969-806X not unique: **3 hits**. Waiting for
fulltext},
abstract = {Analysis of the recently measured absorption spectra of
molecular HI at K and L edges of iodine, in parallel
withpreviously measured spectra of noble gas Xe and the K
edge spectrum of atomic I, is presented. A strongdependence
of some valence multielectron photoexcitation features on
the orbital momentum of the core vacancyis found, attributed
to the change of the symmetry of the HI molecule: the
shake-up coexcitation of avalence electron to a free
molecular orbital is much stronger at L3 than L1 edge. The
effect of angular momentumof the core hole on the shake
processes of deeper multielectron photoexcitations is found
negligible. Both HI andXe exhibit a much weaker one-electron
transition [1s]6p than monatomic I. At the K edge, the
strength ofcoexcitations of 4d, 4p and 3d subshells in
atomic I is close to the HI and Xe. The same is found for HI
and Xe atthe L edges, due to a weak contribution of the
additional free molecular orbital in HI.},
cin = {FS DOOR-User},
ddc = {530},
cid = {$I:(DE-H253)FS_DOOR-User-20241023$},
pnm = {6G3 - PETRA III (DESY) (POF4-6G3) / FS-Proposal: I-20180356
EC (I-20180356-EC) / CALIPSOplus - Convenient Access to
Light Sources Open to Innovation, Science and to the World
(730872)},
pid = {G:(DE-HGF)POF4-6G3 / G:(DE-H253)I-20180356-EC /
G:(EU-Grant)730872},
experiment = {EXP:(DE-H253)P-P65-20150101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:001411244200001},
doi = {10.1016/j.radphyschem.2025.112509},
url = {https://bib-pubdb1.desy.de/record/620187},
}