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000620187 1001_ $$0P:(DE-H253)PIP1015370$$aHauko, R.$$b0$$eCorresponding author
000620187 245__ $$aIodine K- and L-edge X-ray absorption spectra of HI: The effect of molecular orbitals and core subshells
000620187 260__ $$aFrankfurt, M.$$bPergamon Press$$c2025
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000620187 520__ $$aAnalysis of the recently measured absorption spectra of molecular HI at K and L edges of iodine, in parallel withpreviously measured spectra of noble gas Xe and the K edge spectrum of atomic I, is presented. A strongdependence of some valence multielectron photoexcitation features on the orbital momentum of the core vacancyis found, attributed to the change of the symmetry of the HI molecule: the shake-up coexcitation of avalence electron to a free molecular orbital is much stronger at L3 than L1 edge. The effect of angular momentumof the core hole on the shake processes of deeper multielectron photoexcitations is found negligible. Both HI andXe exhibit a much weaker one-electron transition [1s]6p than monatomic I. At the K edge, the strength ofcoexcitations of 4d, 4p and 3d subshells in atomic I is close to the HI and Xe. The same is found for HI and Xe atthe L edges, due to a weak contribution of the additional free molecular orbital in HI.
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000620187 7001_ $$aGomilšek, J. Padežnik$$b1
000620187 7001_ $$0P:(DE-H253)PIP1008407$$aKodre, A.$$b2
000620187 7001_ $$0P:(DE-H253)PIP1008387$$aArčon, I.$$b3
000620187 7001_ $$0P:(DE-H253)PIP1093529$$aLuin, U.$$b4
000620187 773__ $$0PERI:(DE-600)2019621-0$$a10.1016/j.radphyschem.2025.112509$$gVol. 229, p. 112509 -$$p112509$$tRadiation physics and chemistry$$v229$$x0969-806X$$y2025
000620187 8564_ $$uhttps://doi.org/10.1016/j.radphyschem.2025.112509
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