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| 001 | 620005 | ||
| 005 | 20250723173208.0 | ||
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| 100 | 1 | _ | |a Wei, Shaolou |0 P:(DE-H253)PIP1105115 |b 0 |
| 245 | _ | _ | |a Reactive vapor-phase dealloying-alloying turns oxides into sustainable bulk nano-structured porous alloys |
| 260 | _ | _ | |a Washington, DC [u.a.] |c 2024 |b Assoc. |
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| 520 | _ | _ | |a For millennia, alloying has been the greatest gift from metallurgy to humankind: a process of mixing elements, propelling our society from the Bronze Age to the Space Age. Dealloying, by contrast, acts like a penalty: a corrosive counteracting process of selectively removing elements from alloys or compounds, degrading their structural integrity over time. We show that when these two opposite metallurgical processes meet in a reactive vapor environment, profound sustainable alloy design opportunities become accessible, enabling bulk nanostructured porous alloys directly from oxides, with zero carbon footprint. We introduce thermodynamically well-grounded treasure maps that turn the intuitive opposition between alloying and dealloying into harmony, facilitating a quantitative approach to navigate synthesis in such an immense design space. We demonstrate this alloy design paradigm by synthesizing nanostructured Fe-Ni-N porous martensitic alloys fully from oxides in a single solid-state process step and substantiating the critical kinetic processes responsible for the desired microstructure. |
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| 536 | _ | _ | |a ROC - Reducing Iron Oxides without Carbon by using Hydrogen-Plasma (101054368) |0 G:(EU-Grant)101054368 |c 101054368 |f ERC-2021-ADG |x 4 |
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| 700 | 1 | _ | |a Ma, Yan |0 P:(DE-H253)PIP1024188 |b 1 |
| 700 | 1 | _ | |a Raabe, Dierk |0 P:(DE-H253)PIP1010873 |b 2 |e Corresponding author |
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