TY - JOUR AU - Zhang, Shutao AU - Zhang, Ming AU - Inhester, Ludger AU - Ueda, Kiyoshi AU - Lucchesse, Robert AU - Zhao, Leshi AU - Zhang, Shuqiao AU - Dong, Bowen AU - Hao, Yajiang AU - Li, Zheng TI - Molecule effect in inner shell sequential doubleionization JO - The journal of chemical physics VL - 163 IS - 2 SN - 0021-9606 CY - Melville, NY PB - American Institute of Physics M1 - PUBDB-2024-07324 SP - 024303 PY - 2025 AB - We present a theoretical framework for the angular distribution of the two emitted photoelectrons in sequential inner shell two-photon double ionization (TPDI) of uniformly distributed molecules. As an example, we numerically calculated the sequential double ionization of the 4d shells of the iodine atom in CH<sub>3</sub>I with a length and velocity gauge and obtained the corresponding angular anisotropy parameters. For comparison, we also compute the anisotropy parameters for atomic xenon. The anisotropy parameter for the second ionization of CH<sub>3</sub>I is strongly influenced by the molecular structure, providing a sensitive probe for photoionization dynamics in polyatomic systems. This study provides a computational code for simulating sequential TPDI processes, enabling one to computationally study the molecular effects in the angular distribution for sequential inner-shell double ionization. LB - PUB:(DE-HGF)16 DO - DOI:10.1063/5.0265297 UR - https://bib-pubdb1.desy.de/record/619024 ER -