% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Li:618856,
      author       = {Li, Dongqi and Zheng, Wenhao and Gali, Sai Manoj and
                      Sobczak, Kamil and Horák, Michal and Polčák, Josef and
                      Lopatik, Nikolaj and Li, Zichao and Zhang, Jiaxu and
                      Sabaghi, Davood and Zhou, Shengqiang and Michałowski,
                      Paweł P. and Zschech, Ehrenfried and Brunner, Eike and
                      Donten, Mikołaj and Šikola, Tomáš and Bonn, Mischa and
                      Wang, Hai I. and Beljonne, David and Yu, Minghao and Feng,
                      Xinliang},
      title        = {{MX}enes with ordered triatomic-layer borate polyanion
                      terminations},
      journal      = {Nature materials},
      volume       = {23},
      number       = {8},
      issn         = {1476-1122},
      address      = {Basingstoke},
      publisher    = {Nature Publishing Group},
      reportid     = {PUBDB-2024-07194},
      pages        = {1085-1092},
      year         = {2024},
      note         = {Waiting for fulltext},
      abstract     = {Surface terminations profoundly influence the intrinsic
                      properties of MXenes, but existing terminations are limited
                      to monoatomic layers or simple groups, showing disordered
                      arrangements and inferior stability. Here we present the
                      synthesis of MXenes with triatomic-layer borate polyanion
                      terminations (OBO terminations) through a flux-assisted
                      eutectic molten etching approach. During the synthesis,
                      Lewis acidic salts act as the etching agent to obtain the
                      MXene backbone, while borax generates BO2− species, which
                      cap the MXene surface with an O–B–O configuration. In
                      contrast to conventional chlorine/oxygen-terminated Nb2C
                      with localized charge transport, OBO-terminated Nb2C
                      features band transport described by the Drude model,
                      exhibiting a 15-fold increase in electrical conductivity and
                      a 10-fold improvement in charge mobility at the d.c. limit.
                      This transition is attributed to surface ordering that
                      effectively mitigates charge carrier backscattering and
                      trapping. Additionally, OBO terminations provide Ti3C2 MXene
                      with substantially enriched Li+-hosting sites and thereby a
                      large charge-storage capacity of 420 mAh g−1. Our
                      findings illustrate the potential of intricate termination
                      configurations in MXenes and their applications for
                      (opto)electronics and energy storage.},
      cin          = {DOOR ; HAS-User},
      ddc          = {610},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {6G3 - PETRA III (DESY) (POF4-6G3) / GrapheneCore3 -
                      Graphene Flagship Core Project 3 (881603) / LIGHT-CAP -
                      MULTI-ELECTRON PROCESSES FOR LIGHT DRIVEN ELECTRODES AND
                      ELECTROLYTES IN CONVERSION AND STORAGE OF SOLAR ENERGY
                      (101017821) / GREENCAP - Graphene, MXene and ionic
                      liquid-based sustainable supercapacitor (101091572) / SFB
                      1415 A10 - Synthese von Definierten, Chiralen 2D Kovalenten
                      Organischen 2D Gerüstverbindungen (A10*) (544187141)},
      pid          = {G:(DE-HGF)POF4-6G3 / G:(EU-Grant)881603 /
                      G:(EU-Grant)101017821 / G:(EU-Grant)101091572 /
                      G:(GEPRIS)544187141},
      experiment   = {EXP:(DE-H253)P-P65-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:38849556},
      UT           = {WOS:001242165900001},
      doi          = {10.1038/s41563-024-01911-2},
      url          = {https://bib-pubdb1.desy.de/record/618856},
}