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@ARTICLE{Funk:617354,
author = {Funk, Julia and Sochor, Benedikt and Koyiloth Vayalil,
Sarathlal and Weller, Horst},
title = {{I}nsights into the formation of {C}d{S}e nanoplatelets
using a flow reactor},
journal = {Nanoscale},
volume = {16},
number = {46},
issn = {2040-3364},
address = {Cambridge},
publisher = {RSC Publ.},
reportid = {PUBDB-2024-06720},
pages = {21309-21316},
year = {2024},
abstract = {In recent years, the anisotropic semiconductor
nanoplatelets (NPLs) gained interest due to their unique
optical properties, which depend primarily on their
thickness. However, the formation mechanism behind the zinc
blende CdSe NPLs remains unclear. Several theories were
presented and discussed, but a concrete mechanism has not
yet been found with evidence. Here, we want to present a
synthesis of CdSe NPLs in a flow reactor with a liquid
precursor, enabling in situ absorbance measurements. The
flow reactor allows for more control in obtaining
early-stage synthesis samples, which were ex situ examined
with optical spectroscopy, transmission electron microscopy,
as well as small-angle and powder X-ray diffraction. Our
results show that CdSe magic size clusters (MSCs) formed
prior to the formation of CdSe NPLs, indicating that these
CdSe MSCs are necessary for the initial CdSe NPLs growth.},
cin = {FS-PETRA-D},
ddc = {600},
cid = {I:(DE-H253)FS-PETRA-D-20210408},
pnm = {632 - Materials – Quantum, Complex and Functional
Materials (POF4-632) / 6G3 - PETRA III (DESY) (POF4-6G3) /
GRK 2536 - GRK 2536: Hybridstrukturen auf der
Nanometerskala: Chemische Konzepte zur Herstellung
heterogener Nanostrukturen mit anisotropen
Materialeigenschaften (NANOHYBRID) (408076438) / LINCHPIN -
A platform to LINk between CHemistry and PhysIcs of
colloidal Nanomaterials (818941) / SINE2020 - World class
Science and Innovation with Neutrons in Europe 2020 –
SINE2020 (654000)},
pid = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G3 /
G:(GEPRIS)408076438 / G:(EU-Grant)818941 /
G:(EU-Grant)654000},
experiment = {EXP:(DE-H253)P-P03-20150101},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:39485379},
UT = {WOS:001345819900001},
doi = {10.1039/D4NR03804E},
url = {https://bib-pubdb1.desy.de/record/617354},
}