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| 001 | 617130 | ||
| 005 | 20250723172638.0 | ||
| 024 | 7 | _ | |a 10.1021/jacs.4c11119 |2 doi |
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| 100 | 1 | _ | |a Niyas, M. A. |0 P:(DE-H253)PIP1094243 |b 0 |
| 245 | _ | _ | |a Ternary $π–π$ Stacking Complexes by Allosteric Regulation in Multilayer Nanographenes |
| 260 | _ | _ | |a Washington, DC |c 2024 |b ACS Publications |
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| 520 | _ | _ | |a Construction of π–π stacking supramolecular complexes with more than two different components is challenging due to the weak and directionless nature of dispersion interactions. Here, we report ternary complexes of a ditopic nanographene tetraimide (1), α-substituted phthalocyanine (Pc), and polyaromatic hydrocarbons (PAHs) in solution and the crystalline state via allosteric regulation. Binding of one Pc gives rise to significant distortion and conformational changes in 1 that in turn lead to the inhibition of the second binding of Pc. The conformational changes associated with first binding allowed an allosteric binding of a third component (PAHs) to form ternary complexes in solution. 1H NMR titration revealed moderately high thermodynamic stability for the ternary complexes in CDCl3. Competition between allosterically regulated ternary complexes ([Pc·1·PAH]) and 1:2 stoichiometric binary complexes of 1 with PAHs ([PAH·1·PAH]) was elucidated. Further, the selective formation of ternary complexes in solution led to the generation of ternary cocrystals from a 1:1:1 mixture of three components in solution. Our work shows that large π-conjugated nanographenes designed with allosteric recognition sites allow the construction of multilayer ternary complexes in solution and the solid state even with dispersive π–π interactions. |
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| 542 | _ | _ | |i 2024-10-18 |2 Crossref |u https://doi.org/10.15223/policy-029 |
| 542 | _ | _ | |i 2024-10-18 |2 Crossref |u https://doi.org/10.15223/policy-037 |
| 542 | _ | _ | |i 2024-10-18 |2 Crossref |u https://doi.org/10.15223/policy-045 |
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| 700 | 1 | _ | |a Shoyama, Kazutaka |0 P:(DE-H253)PIP1094122 |b 1 |
| 700 | 1 | _ | |a Wuerthner, Frank |0 P:(DE-H253)PIP1094247 |b 2 |e Corresponding author |
| 773 | 1 | 8 | |a 10.1021/jacs.4c11119 |b American Chemical Society (ACS) |d 2024-10-18 |n 43 |p 29728-29734 |3 journal-article |2 Crossref |t Journal of the American Chemical Society |v 146 |y 2024 |x 0002-7863 |
| 773 | _ | _ | |a 10.1021/jacs.4c11119 |g Vol. 146, no. 43, p. 29728 - 29734 |0 PERI:(DE-600)1472210-0 |n 43 |p 29728-29734 |t Journal of the American Chemical Society |v 146 |y 2024 |x 0002-7863 |
| 856 | 4 | _ | |y Published on 2024-10-18. Available in OpenAccess from 2025-10-18. |u https://bib-pubdb1.desy.de/record/617130/files/ja-2024-11119q.R1_Manuscript_revised.pdf |
| 856 | 4 | _ | |y Restricted |u https://bib-pubdb1.desy.de/record/617130/files/niyas-et-al-2024-ternary-%CF%80-%CF%80-stacking-complexes-by-allosteric-regulation-in-multilayer-nanographenes-1.pdf |
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