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@ARTICLE{Yoshikawa:616887,
author = {Yoshikawa, Kazuki and Kanno, Manabu and Xue, Hao and
Kishimoto, Naoki and Goto, Soki and Ota, Fukiko and Tamura,
Yoshiaki and Trinter, Florian and Fehre, Kilian and Kaiser,
Leon and Stindl, Jonathan and Tsitsonis, Dimitrios and
Schoeffler, Markus and Doerner, Reinhard and Boll, Rebecca
and Erk, Benjamin and Mazza, Tommaso and Mullins, Terence
and Rivas, Daniel and Schmidt, Philipp and Usenko, Sergey
and Meyer, Michael and Wang, Enliang and Rolles, Daniel and
Rudenko, Artem and Kukk, Edwin and Jahnke, Till and
Diaz-Tendero, Sergio and Martin, Fernando and Hatada,
Keisuke and Ueda, Kiyoshi},
title = {{T}ime-resolved photoelectron diffraction imaging of
methanol photodissociation involving molecular hydrogen
ejection},
journal = {Physical chemistry, chemical physics},
volume = {26},
number = {38},
issn = {1463-9076},
address = {Cambridge},
publisher = {RSC Publ.},
reportid = {PUBDB-2024-06568},
pages = {25118-25130},
year = {2024},
abstract = {Imaging ultrafast atomic and molecular hydrogen motion with
femtosecond time resolution is a challenge for ultrafast
spectroscopy due to the low mass and small scattering cross
section of the moving neutral hydrogen atoms and molecules.
Here, we propose time- and momentum-resolved photoelectron
diffraction (TMR-PED) as a way to overcome limitations of
existing methodologies and illustrate its performance using
a prototype molecular dissociation process involving the
sequential ejection of a neutral hydrogen molecule and a
proton from the methanol dication. By combining
state-of-the-art molecular dynamics and electron-scattering
methods, we show that TMR-PED allows for direct imaging of
hydrogen atoms in action. More specifically, the fingerprint
of hydrogen dynamics reflects the time evolution of
polarization-averaged molecular-frame photoelectron angular
distributions (PA-MFPADs) as would be recorded in X-ray
pump/X-ray probe experiments with few-femtosecond
resolution. We present the results of two precursor
experiments that support the feasibility of this approach.},
cin = {$XFEL_E2_SQS$ / FS-PETRA-S / DOOR ; HAS-User},
ddc = {540},
cid = {$I:(DE-H253)XFEL_E2_SQS-20210408$ /
I:(DE-H253)FS-PETRA-S-20210408 /
I:(DE-H253)HAS-User-20120731},
pnm = {631 - Matter – Dynamics, Mechanisms and Control
(POF4-631) / 6G3 - PETRA III (DESY) (POF4-6G3) / DFG project
G:(GEPRIS)509471550 - Dynamik photoionisations-induzierter
Prozesse in laser-präparierten Molekülen in der Gasphase
und der wässrigen Phase (509471550) / FS-Proposal:
I-20180746 EC (I-20180746-EC) / DFG project
G:(GEPRIS)390715994 - EXC 2056: CUI: Advanced Imaging of
Matter (390715994) / SFB 1319 B01 - Chirale Erkennung und
Manipulation von transienten Molekülen mittels
Coulombex-plosion und Photoelektronenbeugung (B01)
(389894813)},
pid = {G:(DE-HGF)POF4-631 / G:(DE-HGF)POF4-6G3 /
G:(GEPRIS)509471550 / G:(DE-H253)I-20180746-EC /
G:(GEPRIS)390715994 / G:(GEPRIS)389894813},
experiment = {EXP:(DE-H253)P-P04-20150101 /
EXP:(DE-H253)XFEL-SQS-20150101},
typ = {PUB:(DE-HGF)16},
pubmed = {39311030},
UT = {WOS:001317801500001},
doi = {10.1039/D4CP01015A},
url = {https://bib-pubdb1.desy.de/record/616887},
}