Home > Publications database > Spectral fingerprinting of aqueous glucose with ultra-broadband vibrational sum-frequency generation spectroscopy at bio-relevant low concentration > print

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100 1 _ |a Luo, Cheng
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245 _ _ |a Spectral fingerprinting of aqueous glucose with ultra-broadband vibrational sum-frequency generation spectroscopy at bio-relevant low concentration
260 _ _ |a Washington, DC
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520 _ _ |a Vibrational modes of glucose spanning from 900 to 1400 cm$^{−1}$ in the molecular fingerprint region have been traced by means of vibrational sum-frequency generation spectroscopy in aqueous solution as a function of glucose concentration. The high sensitivity is enabled by a 200 kHz few-cycle mid-infrared optical parametric chirped-pulse amplifier (OPCPA). The OPCPA generates broadband pulses (from 7 to 11 µm) centered at 9 µm with 114 fs pulse duration, at a high average power of 245 mW and high pulse energy of 1.2 µJ. The achieved performance of the spectrometer is benchmarked by probing the carbon-oxygen bond stretching mode at 1035 cm using a biologically relevant low sample concentration of 10 mM.
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700 1 _ |a Vasudevan Namboodiri, Mahesh
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700 1 _ |a Schulz, Michael
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700 1 _ |a Riedel, Robert
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700 1 _ |a Prandolini, Mark
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700 1 _ |a Laarmann, Tim
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773 _ _ |a 10.1364/OE.544862
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