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000615365 1001_ $$0P:(DE-HGF)0$$aGarain, Swadhin$$b0
000615365 245__ $$a2,3 : 6,7‐Naphthalene Bis(dicarboximide) Cyclophane: A Photofunctional Host for Ambient Delayed Fluorescence in Solution
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000615365 520__ $$aHarvesting triplet excitons of heavy atom-free purely organic chromophores under aerated conditions is challenging due to the quenching of long-lived triplet states by molecular oxygen and vibrational dissipation. Herein, we show a supramolecular approach of triplet harvesting via mitigating quenching pathways of a triplet harvester. Specifically, we used a host–guest system based on 2,3 : 6,7-naphthalene bis(dicarboximide)-derived cyclophane (NBICy) and carbazole derivative (EtCz). Complexation studies and single-crystal X-ray analysis showed the formation of a rigid host–guest complex (K≈10$^4$ M$^{−1}$ in CCl$_4$), resulting in triplet-exciton stabilization under aerated conditions via mitigating vibrational interference and oxygen quenching. Photophysical studies elucidate the delayed fluorescence emission from the charge-transfer state (1CT) with a quantum yield (QY) of 6–8 % under ambient conditions which increased up to 36 % in an inert atmosphere. 
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000615365 7001_ $$0P:(DE-HGF)0$$aLi, Pei-Lun$$b1
000615365 7001_ $$0P:(DE-H253)PIP1094122$$aShoyama, Kazutaka$$b2
000615365 7001_ $$0P:(DE-H253)PIP1094247$$aWuerthner, Frank$$b3$$eCorresponding author
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