Home > Publications database > Study of the Structure of Zn and Na Borophosphate Glasses Using X-ray and Neutron Scattering Techniques > print

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100 1 _ |a Hoppe, Uwe
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245 _ _ |a Study of the Structure of Zn and Na Borophosphate Glasses Using X-ray and Neutron Scattering Techniques
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520 _ _ |a The atomic structures of Zn and Na borophosphate glasses were studied using X-ray and neutron scattering techniques. Peaks assigned to the B−O, P−O, and O−O distances confirm that only BO4 units co-exist with the PO4 tetrahedra. The Zn−O and Na−O coordination numbers are found to be a little larger than four. The narrowest peaks of the Zn−O first-neighbor distances exist for the glasses along a line connecting the Zn(PO$_3$)$_2$ and BPO$_4$ compositions (50 mol% P$_2$O$_5$), which is explained by networks of ZnO$_4$, BO$_4$, and PO$_4$ tetrahedra with twofold coordinated oxygens. The calculated amounts of available oxygen support this interpretation. Broadened peaks occur for glasses with lower P$_2$O$_5$ contents, which is consistent with the presence of threefold coordinated oxygens. The two distinct P−O peak components of the Zn and Na borophosphate glasses differ in their relative abundances. This is interpreted as follows: Na$^+$ cations coordinate oxygens in some P−O−B bridges, which is something not seen for the Zn$< {2+}$ ions.
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