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@ARTICLE{Hoppe:614265,
      author       = {Hoppe, Uwe and Freudenberger, Parker T. and Brow, Richard
                      K. and Bednarcik, Jozef and Hannon, Alex C.},
      title        = {{S}tudy of the {S}tructure of {Z}n and {N}a {B}orophosphate
                      {G}lasses {U}sing {X}-ray and {N}eutron {S}cattering
                      {T}echniques},
      journal      = {Solids},
      volume       = {5},
      number       = {3},
      issn         = {2673-6497},
      address      = {Basel},
      publisher    = {MDPI},
      reportid     = {PUBDB-2024-05805},
      pages        = {355-374},
      year         = {2024},
      abstract     = {The atomic structures of Zn and Na borophosphate glasses
                      were studied using X-ray and neutron scattering techniques.
                      Peaks assigned to the B−O, P−O, and O−O distances
                      confirm that only BO4 units co-exist with the PO4
                      tetrahedra. The Zn−O and Na−O coordination numbers are
                      found to be a little larger than four. The narrowest peaks
                      of the Zn−O first-neighbor distances exist for the glasses
                      along a line connecting the Zn(PO$_3$)$_2$ and BPO$_4$
                      compositions (50 mol\% P$_2$O$_5$), which is explained by
                      networks of ZnO$_4$, BO$_4$, and PO$_4$ tetrahedra with
                      twofold coordinated oxygens. The calculated amounts of
                      available oxygen support this interpretation. Broadened
                      peaks occur for glasses with lower P$_2$O$_5$ contents,
                      which is consistent with the presence of threefold
                      coordinated oxygens. The two distinct P−O peak components
                      of the Zn and Na borophosphate glasses differ in their
                      relative abundances. This is interpreted as follows: Na$^+$
                      cations coordinate oxygens in some P−O−B bridges, which
                      is something not seen for the Zn$< {2+}$ ions.},
      cin          = {FS-PE / DOOR ; HAS-User},
      ddc          = {540},
      cid          = {I:(DE-H253)FS-PE-20120731 / I:(DE-H253)HAS-User-20120731},
      pnm          = {632 - Materials – Quantum, Complex and Functional
                      Materials (POF4-632) / 6G3 - PETRA III (DESY) (POF4-6G3)},
      pid          = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G3},
      experiment   = {EXP:(DE-H253)P-P02.1-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:001323758500001},
      doi          = {10.3390/solids5030024},
      url          = {https://bib-pubdb1.desy.de/record/614265},
}