TY  - JOUR
AU  - Yang, Haotian
AU  - Wang, Xifan
AU  - Praetz, Sebastian
AU  - Pang, Shumin
AU  - Görke, Oliver
AU  - Bekheet, Maged F.
AU  - Hanaor, Dorian A. H.
AU  - Gurlo, Aleksander
TI  - Photolithographic additive manufacturing of high-entropy perovskite oxides from synthesized multimetallic polymeric precursors
JO  - Journal of the European Ceramic Society
VL  - 45
IS  - 1
SN  - 0955-2219
CY  - Amsterdam [u.a.]
PB  - Elsevier Science
M1  - PUBDB-2024-05655
SP  - 116812 
PY  - 2025
AB  - In this work, the synthesis of high-entropy perovskite-type oxides from multimetallic polymeric precursors and their shaping by photolithographic additive manufacturing is investigated. Thermosets with well-controlled complex geometries are produced by digital light processing using the multimetallic organic-inorganic hybrid resin developed in this work and converted into ceramics by thermal debinding and sintering. The high-entropy perovskite-type oxides are produced at 1500 °C, they retain the printed geometry with high shape fidelity. The orthorhombic crystal structure is identified by the Rietveld refinement of high-resolution synchrotron X-ray data; elemental and spectroscopic characterizations suggest the composition Sr(Ti<sub>0.22</sub>Zr<sub>0.22</sub>Hf<sub>0.23</sub>Mn<sub>0.15</sub>Sn<sub>0.18</sub>)O<sub>2.85</sub>. The use of aqueous polyethylene glycol as a binder and porogen greatly reduces the formation of cracks and creates evenly distributed micropores, which leads to improved compressive strength of the specimens. The compressive strength of 0.94 MPa is highest for materials printed from the resins with 3 wt
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:001295628100001
DO  - DOI:10.1016/j.jeurceramsoc.2024.116812
UR  - https://bib-pubdb1.desy.de/record/613876
ER  -