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@ARTICLE{Dupuy:613830,
      author       = {Dupuy, Remi and Buttersack, Tillmann and Trinter, Florian
                      and Richter, Clemens and Gholami, Shirin and Björneholm,
                      Olle and Hergenhahn, Uwe and Winter, Bernd and Bluhm,
                      Hendrik},
      title        = {{T}he solvation shell probed by resonant intermolecular
                      {C}oulombic decay},
      journal      = {Nature Communications},
      volume       = {15},
      number       = {1},
      issn         = {2041-1723},
      address      = {[London]},
      publisher    = {Nature Publishing Group UK},
      reportid     = {PUBDB-2024-05636},
      pages        = {6926},
      year         = {2024},
      abstract     = {Molecules involved in solvation shells have properties
                      differing from those of the bulk solvent, which can in turn
                      affect reactivity. Among key properties of these molecules
                      are their nature and electronic structure. Widely used tools
                      to characterize this type of property are X-ray-based
                      spectroscopies, which, however, usually lack the capability
                      to selectively probe the solvation-shell molecules. A class
                      of X-ray triggered “non-local” processes has the
                      recognized potential to provide this selectivity.
                      Intermolecular Coulombic decay (ICD) and related processes
                      involve neighbouring molecules in the decay of the
                      X-ray-excited target, and are thus naturally sensitive to
                      its immediate environment. Applying electron spectroscopy to
                      aqueous solutions, we explore the resonant flavours of ICD
                      and demonstrate how it can inform on the first solvation
                      shell of excited solvated cations. One particular ICD
                      process turns out to be a potent marker of the formation of
                      ion pairs. Another gives a direct access to the electron
                      binding energies of the water molecules in the first
                      solvation shell, a quantity previously elusive to direct
                      measurements. The resonant nature of the processes makes
                      them readily measurable, providing powerful new
                      spectroscopic tools.},
      cin          = {DOOR ; HAS-User},
      ddc          = {500},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {6G3 - PETRA III (DESY) (POF4-6G3) / FS-Proposal: I-20211422
                      (I-20211422) / FS-Proposal: I-20220291 (I-20220291) /
                      FS-Proposal: I-20221212 (I-20221212) / AQUACHIRAL - Chiral
                      aqueous-phase chemistry (883759) / SWEDEN-DESY - SWEDEN-DESY
                      Collaboration $(2020_Join2-SWEDEN-DESY)$},
      pid          = {G:(DE-HGF)POF4-6G3 / G:(DE-H253)I-20211422 /
                      G:(DE-H253)I-20220291 / G:(DE-H253)I-20221212 /
                      G:(EU-Grant)883759 / $G:(DE-HGF)2020_Join2-SWEDEN-DESY$},
      experiment   = {EXP:(DE-H253)P-P04-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:39138192},
      UT           = {WOS:001291270300025},
      doi          = {10.1038/s41467-024-51417-3},
      url          = {https://bib-pubdb1.desy.de/record/613830},
}