Home > Publications database > Understanding the role of supported Rh atoms and clusters during hydroformylation and CO hydrogenation reactions with in situ / operando XAS and DRIFT spectroscopy > print

001     611720
005     20250723171923.0
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024 7 _ |a 2041-6520
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100 1 _ |a Sarma, Bidyut Bikash
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245 _ _ |a Understanding the role of supported Rh atoms and clusters during hydroformylation and CO hydrogenation reactions with in situ / operando XAS and DRIFT spectroscopy
260 _ _ |a Cambridge
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520 _ _ |a Supported Rh single-atoms and clusters on CeO2, MgO, and ZrO2 were investigated as catalysts for hydroformylation of ethylene to propionaldehyde and CO hydrogenation to methanol/ethanol with in situ/operando diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and X-ray absorption spectroscopy (XAS). Under hydroformylation reaction conditions, operando spectroscopic investigations unravel the presence of both single atoms and clusters and detected at first propanal and then methanol. We find that the formation of methanol is associated with CO hydrogenation over Rh clusters which was further confirmed under CO hydrogenation conditions at elevated pressure. The activity of catalysts synthesized via a precipitation (PP) method over various supports towards the hydroformylation reaction follows the order: Rh/ZrO2 > Rh/CeO2 > Rh/MgO. Comparing Rh/CeO2 catalysts synthesized via different methods, catalysts prepared by flame spray pyrolysis (FSP) showed catalytic activity for the hydroformylation reaction at lower temperatures (413 K), whereas catalysts prepared by wet impregnation (WI) showed the highest stability. These results not only provide fundamental insights into the atomistic level of industrially relevant reactions but also pave the way for a rational design of new catalysts in the future.
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536 _ _ |a SFB 1441 B03 - In situ/operando-Charakterisierung von Edelmetallclustern und Partikeln auf Metalloxiden unter Reaktionsbedingungen (B03) (446701131)
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700 1 _ |a Neukum, Dominik
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700 1 _ |a Doronkin, Dmitry
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999 C 5 |a 10.1021/cr3001803
|9 -- missing cx lookup --
|1 Franke
|p 5675 -
|2 Crossref
|t Chem. Rev.
|v 112
|y 2012
999 C 5 |a 10.1021/ja070395n
|9 -- missing cx lookup --
|1 Sparta
|p 8487 -
|2 Crossref
|t J. Am. Chem. Soc.
|v 129
|y 2007
999 C 5 |a 10.1080/01614949108020298
|9 -- missing cx lookup --
|1 Forzatti
|p 109 -
|2 Crossref
|t Catal. Rev.
|v 33
|y 1991
999 C 5 |a 10.1016/0920-5861(87)80002-0
|9 -- missing cx lookup --
|1 Xiaoding
|p 125 -
|2 Crossref
|t Catal. Today
|v 2
|y 1987
999 C 5 |a 10.1039/C6CS00324A
|9 -- missing cx lookup --
|1 Luk
|p 1358 -
|2 Crossref
|t Chem. Soc. Rev.
|v 46
|y 2017
999 C 5 |a 10.1016/0021-9517(86)90340-4
|9 -- missing cx lookup --
|1 van der Lee
|p 522 -
|2 Crossref
|t J. Catal.
|v 98
|y 1986
999 C 5 |a 10.1021/acscatal.2c04349
|9 -- missing cx lookup --
|1 Suvarna
|p 15373 -
|2 Crossref
|t ACS Catal.
|v 12
|y 2022
999 C 5 |a 10.1002/anie.201607885
|9 -- missing cx lookup --
|1 Lang
|p 16054 -
|2 Crossref
|t Angew. Chem., Int. Ed.
|v 55
|y 2016
999 C 5 |a 10.1021/jacs.9b12171
|9 -- missing cx lookup --
|1 Amsler
|p 5087 -
|2 Crossref
|t J. Am. Chem. Soc.
|v 142
|y 2020
999 C 5 |a 10.1038/ncomms14036
|9 -- missing cx lookup --
|1 Wang
|p 14036 -
|2 Crossref
|t Nat. Commun.
|v 7
|y 2016
999 C 5 |a 10.1007/s11705-017-1672-9
|9 -- missing cx lookup --
|1 Li
|p 113 -
|2 Crossref
|t Front. Chem. Sci. Eng.
|v 12
|y 2018
999 C 5 |a 10.3390/catal10050510
|9 -- missing cx lookup --
|1 Hanf
|p 1 -
|2 Crossref
|t Catalysts
|v 10
|y 2020
999 C 5 |a 10.1021/ar300361m
|9 -- missing cx lookup --
|1 Yang
|p 1740 -
|2 Crossref
|t Acc. Chem. Res.
|v 46
|y 2013
999 C 5 |a 10.1038/s41570-018-0010-1
|9 -- missing cx lookup --
|1 Wang
|p 65 -
|2 Crossref
|t Nat. Rev. Chem.
|v 2
|y 2018
999 C 5 |a 10.1038/s41586-022-05075-4
|9 -- missing cx lookup --
|1 Ro
|p 287 -
|2 Crossref
|t Nature
|v 609
|y 2022
999 C 5 |a 10.1021/acs.jpcc.2c07263
|9 -- missing cx lookup --
|1 Sarma
|p 3032 -
|2 Crossref
|t J. Phys. Chem. C
|v 127
|y 2023
999 C 5 |a 10.1021/acscatal.9b04214
|9 -- missing cx lookup --
|1 Liu
|p 10626 -
|2 Crossref
|t ACS Catal.
|v 9
|y 2019
999 C 5 |a 10.31635/ccschem.021.202101063
|9 -- missing cx lookup --
|1 Ding
|p 1814 -
|2 Crossref
|t CCS Chem.
|v 3
|y 2021
999 C 5 |a 10.1021/acscatal.2c06321
|9 -- missing cx lookup --
|1 Zakem
|p 5502 -
|2 Crossref
|t ACS Catal.
|v 13
|y 2023
999 C 5 |a 10.1021/acscatal.3c00810
|9 -- missing cx lookup --
|1 Zheng
|p 7243 -
|2 Crossref
|t ACS Catal.
|v 13
|y 2023
999 C 5 |a 10.1021/jacs.2c11075
|9 -- missing cx lookup --
|1 Qi
|p 2911 -
|2 Crossref
|t J. Am. Chem. Soc.
|v 145
|y 2023
999 C 5 |a 10.1021/acscatal.9b02111
|9 -- missing cx lookup --
|1 Ro
|p 10899 -
|2 Crossref
|t ACS Catal.
|v 9
|y 2019
999 C 5 |a 10.1038/s41467-023-42938-4
|9 -- missing cx lookup --
|1 Zhao
|p 7174 -
|2 Crossref
|t Nat. Commun.
|v 14
|y 2023
999 C 5 |a 10.1021/acscatal.0c05002
|9 -- missing cx lookup --
|1 Schumann
|p 5189 -
|2 Crossref
|t ACS Catal.
|v 11
|y 2021
999 C 5 |a 10.1021/jacs.5b12087
|9 -- missing cx lookup --
|1 Yang
|p 3705 -
|2 Crossref
|t J. Am. Chem. Soc.
|v 138
|y 2016
999 C 5 |a 10.1039/b414039g
|9 -- missing cx lookup --
|1 Spivey
|p 1514 -
|2 Crossref
|t Chem. Soc. Rev.
|v 36
|y 2007
999 C 5 |a 10.1002/anie.201607552
|9 -- missing cx lookup --
|1 Foit
|p 5402 -
|2 Crossref
|t Angew. Chem., Int. Ed.
|v 56
|y 2017
999 C 5 |a 10.1039/C3CS60395D
|9 -- missing cx lookup --
|1 Pakhare
|p 7813 -
|2 Crossref
|t Chem. Soc. Rev.
|v 43
|y 2014
999 C 5 |a 10.1039/C7EE00071E
|9 -- missing cx lookup --
|1 Sheng
|p 1180 -
|2 Crossref
|t Energy Environ. Sci.
|v 10
|y 2017
999 C 5 |a 10.1002/anie.202108492
|9 -- missing cx lookup --
|1 Lam
|p 23306 -
|2 Crossref
|t Angew. Chem., Int. Ed.
|v 60
|y 2021
999 C 5 |a 10.1016/j.ijhydene.2008.12.023
|9 -- missing cx lookup --
|1 He
|p 1342 -
|2 Crossref
|t Int. J. Hydrogen Energy
|v 34
|y 2009
999 C 5 |1 Surisetty
|y 2011
|2 Crossref
|o Surisetty 2011
999 C 5 |a 10.1021/acscatal.8b01391
|9 -- missing cx lookup --
|1 Ao
|p 7025 -
|2 Crossref
|t ACS Catal.
|v 8
|y 2018
999 C 5 |a 10.1021/acscatal.2c02103
|9 -- missing cx lookup --
|1 Wu
|p 12253 -
|2 Crossref
|t ACS Catal.
|v 12
|y 2022
999 C 5 |a 10.1016/j.jcat.2022.08.031
|9 -- missing cx lookup --
|1 Schumann
|p 90 -
|2 Crossref
|t J. Catal.
|v 414
|y 2022
999 C 5 |a 10.1021/acscatal.2c02353
|9 -- missing cx lookup --
|1 Deimel
|p 7907 -
|2 Crossref
|t ACS Catal.
|v 12
|y 2022
999 C 5 |a 10.1073/pnas.1006635107
|9 -- missing cx lookup --
|1 McClure
|p 931 -
|2 Crossref
|t Proc. Natl. Acad. Sci. U. S. A.
|v 108
|y 2011
999 C 5 |a 10.1021/cs2001048
|9 -- missing cx lookup --
|1 Gupta
|p 641 -
|2 Crossref
|t ACS Catal.
|v 1
|y 2011
999 C 5 |a 10.1016/j.cattod.2009.01.038
|9 -- missing cx lookup --
|1 Fang
|p 133 -
|2 Crossref
|t Catal. Today
|v 147
|y 2009
999 C 5 |a 10.1016/S0920-5861(99)00246-1
|9 -- missing cx lookup --
|1 Herman
|p 233 -
|2 Crossref
|t Catal. Today
|v 55
|y 2000
999 C 5 |a 10.1016/S1872-2067(11)60496-8
|9 -- missing cx lookup --
|1 Xiao
|p 116 -
|2 Crossref
|t Chin. J. Catal.
|v 34
|y 2013
999 C 5 |1 Breslow
|y 1960
|2 Crossref
|o Breslow 1960
999 C 5 |a 10.1021/ja01480a017
|9 -- missing cx lookup --
|1 Heck
|p 4023 -
|2 Crossref
|t J. Am. Chem. Soc.
|v 83
|y 1961
999 C 5 |a 10.1007/s11244-005-2897-2
|9 -- missing cx lookup --
|1 Chuang
|p 225 -
|2 Crossref
|t Top. Catal.
|v 32
|y 2005
999 C 5 |a 10.1016/0021-9517(92)90058-P
|9 -- missing cx lookup --
|1 Chuang
|p 618 -
|2 Crossref
|t J. Catal.
|v 135
|y 1992
999 C 5 |a 10.1002/anie.201701115
|9 -- missing cx lookup --
|1 Xiong
|p 8986 -
|2 Crossref
|t Angew. Chem., Int. Ed.
|v 56
|y 2017
999 C 5 |a 10.1038/s41467-019-12843-w
|9 -- missing cx lookup --
|1 Akri
|p 5181 -
|2 Crossref
|t Nat. Commun.
|v 10
|y 2019
999 C 5 |a 10.1039/D1TA00421B
|9 -- missing cx lookup --
|1 Sarma
|p 8401 -
|2 Crossref
|t J. Mater. Chem. A
|v 9
|y 2021
999 C 5 |a 10.1021/ja5128133
|9 -- missing cx lookup --
|1 Matsubu
|p 3076 -
|2 Crossref
|t J. Am. Chem. Soc.
|v 137
|y 2015
999 C 5 |a 10.1021/jacs.8b07615
|9 -- missing cx lookup --
|1 Aitbekova
|p 13736 -
|2 Crossref
|t J. Am. Chem. Soc.
|v 140
|y 2018
999 C 5 |a 10.1006/jcat.2001.3211
|9 -- missing cx lookup --
|1 Grunwaldt
|p 321 -
|2 Crossref
|t J. Catal.
|v 200
|y 2001
999 C 5 |a 10.1126/science.aaf8800
|9 -- missing cx lookup --
|1 Jones
|p 150 -
|2 Crossref
|t Science
|v 353
|y 2016
999 C 5 |a 10.1002/anie.201915255
|9 -- missing cx lookup --
|1 Sarma
|p 5806 -
|2 Crossref
|t Angew. Chem., Int. Ed.
|v 59
|y 2020
999 C 5 |a 10.1021/acsanm.1c02194
|9 -- missing cx lookup --
|1 Galdeano-Ruano
|p 10743 -
|2 Crossref
|t ACS Appl. Nano Mater.
|v 4
|y 2021
999 C 5 |a 10.1039/C5CS00011D
|9 -- missing cx lookup --
|1 Koirala
|p 3053 -
|2 Crossref
|t Chem. Soc. Rev.
|v 45
|y 2016
999 C 5 |a 10.2533/chimia.2024.288
|9 -- missing cx lookup --
|1 Sarma
|p 288 -
|2 Crossref
|t Chimia
|v 78
|y 2024
999 C 5 |a 10.1021/acs.chemrev.2c00495
|9 -- missing cx lookup --
|1 Sarma
|p 379 -
|2 Crossref
|t Chem. Rev.
|v 123
|y 2023
999 C 5 |a 10.1016/j.apcata.2015.01.047
|9 -- missing cx lookup --
|1 Cavusoglu
|p 381 -
|2 Crossref
|t Appl. Catal., A
|v 504
|y 2015
999 C 5 |a 10.1038/s41929-021-00621-1
|9 -- missing cx lookup --
|1 Muravev
|p 469 -
|2 Crossref
|t Nat. Catal.
|v 4
|y 2021
999 C 5 |a 10.1021/cm050538+
|9 -- missing cx lookup --
|1 Stark
|p 3352 -
|2 Crossref
|t Chem. Mater.
|v 17
|y 2005
999 C 5 |a 10.1021/acscatal.3c01116
|9 -- missing cx lookup --
|1 Finzel
|p 6462 -
|2 Crossref
|t ACS Catal.
|v 13
|y 2023
999 C 5 |a 10.1021/j100202a068
|9 -- missing cx lookup --
|1 Basini
|p 9431 -
|2 Crossref
|t J. Phys. Chem.
|v 96
|y 1992
999 C 5 |a 10.1021/acs.jpcc.1c06784
|9 -- missing cx lookup --
|1 Meunier
|p 21810 -
|2 Crossref
|t J. Phys. Chem. C
|v 125
|y 2021
999 C 5 |a 10.1021/jacs.7b11010
|9 -- missing cx lookup --
|1 Kwon
|p 17694 -
|2 Crossref
|t J. Am. Chem. Soc.
|v 139
|y 2017
999 C 5 |a 10.1021/jacs.0c03627
|9 -- missing cx lookup --
|1 Sarma
|p 14890 -
|2 Crossref
|t J. Am. Chem. Soc.
|v 142
|y 2020
999 C 5 |a 10.1039/b925206a
|9 -- missing cx lookup --
|1 Beale
|p 5562 -
|2 Crossref
|t Phys. Chem. Chem. Phys.
|v 12
|y 2010
999 C 5 |a 10.1016/j.jcat.2011.03.015
|9 -- missing cx lookup --
|1 Ligthart
|p 206 -
|2 Crossref
|t J. Catal.
|v 280
|y 2011

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