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@ARTICLE{Garg:611717,
author = {Garg, Diksha and Chopra, Pragya and Lee, Jason W. L. and
Tikhonov, Denis and Kumar, Sonu and Akcaalan, Oender and
Allum, Felix and Boll, Rebecca and Butler, Alexander A. and
Erk, Benjamin and Gougoula, Eva and Gruet, Sébastien P. and
He, Lanhai and Heathcote, David and Jones, Ellen and Kazemi,
Mehdi M. and Lahl, Jan and Lemmens, Alexander K. and Liu,
Zhihao and Loru, Donatella and Maclot, Sylvain and Mason,
Robert and Merrick, James and Muller, Erland and Mullins,
Terry and Papadopoulou, Christina C. and Passow, Christopher
and Peschel, Jasper and Plach, Marius and Ramm, Daniel and
Robertson, Patrick and Rompotis, Dimitrios and Simao,
Alcides and Steber, Amanda L. and Tajalli, Ayhan and
Tul-Noor, Atia and Vadassery, Nidin and Vinklarek, Ivo S.
and Techert, Simone and Küpper, Jochen and Rijs, Anouk and
Rolles, Daniel and Brouard, Mark and Bari, Sadia and
Eng-Johnsson, Per and Vallance, Claire and Burt, Michael and
Manschwetus, Bastian and Schnell, Melanie},
title = {{U}ltrafast dynamics of fluorene initiated by highly
intense laser fields},
reportid = {PUBDB-2024-05030},
year = {2024},
abstract = {We present an investigation of the ultrafast dynamics of
the polycyclic aromatic hydrocarbon fluorene initiated by an
intense femtosecond near- infrared laser pulse (810 nm) and
probed by a weak visible pulse (405 nm). Using a
multichannel detection scheme (mass spectra, electron and
ion velocity-map imaging), we provide a full disentanglement
of the complex dynamics of the vibronically excited parent
molecule, its excited ionic states, and fragments. We
observed various channels resulting from the strong-field
ionization regime. In particular, we observed the formation
of the unstable tetracation of fluorene, above-threshold
ionization features in the photoelectron spectra, and
evidence of ubiquitous secondary fragmentation. We produced
a global fit of all observed time-dependent photoelectron
and photoion channels. This global fit includes four parent
ions extracted from the mass spectra, 15
kinetic-energy-resolved ionic fragments extracted from ion
velocity map imaging, and five photoelectron channels
obtained from electron velocity map imaging. The fit allowed
for the extraction of 60 lifetimes of various metastable
photoinduced intermediates.},
cin = {FS-SMP / FS-CFEL-CMI / FS-SCS / FS-FL / FS-LA},
cid = {I:(DE-H253)FS-SMP-20171124 /
I:(DE-H253)FS-CFEL-CMI-20220405 / I:(DE-H253)FS-SCS-20131031
/ I:(DE-H253)FS-FL-20120731 / I:(DE-H253)FS-LA-20130416},
pnm = {631 - Matter – Dynamics, Mechanisms and Control
(POF4-631) / 6G2 - FLASH (DESY) (POF4-6G2) / DFG project
390715994 - EXC 2056: CUI: Advanced Imaging of Matter
(390715994) / ASTROROT - Unraveling interstellar chemistry
with broadband microwave spectroscopy and next-generation
telescope arrays (638027) / CALIPSOplus - Convenient Access
to Light Sources Open to Innovation, Science and to the
World (730872) / FS-Proposal: F-20170540 (F-20170540) /
FS-Proposal: F-20211752 (F-20211752)},
pid = {G:(DE-HGF)POF4-631 / G:(DE-HGF)POF4-6G2 /
G:(GEPRIS)390715994 / G:(EU-Grant)638027 /
G:(EU-Grant)730872 / G:(DE-H253)F-20170540 /
G:(DE-H253)F-20211752},
experiment = {EXP:(DE-H253)F-BL1-20150101},
typ = {PUB:(DE-HGF)25},
doi = {10.26434/chemrxiv-2023-18w5m-v3},
url = {https://bib-pubdb1.desy.de/record/611717},
}