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| 001 | 611712 | ||
| 005 | 20240714063926.0 | ||
| 024 | 7 | _ | |a arXiv:1905.07166 |2 arXiv |
| 024 | 7 | _ | |a altmetric:72688341 |2 altmetric |
| 024 | 7 | _ | |a pmid:31922822 |2 pmid |
| 037 | _ | _ | |a PUBDB-2024-05026 |
| 041 | _ | _ | |a English |
| 082 | _ | _ | |a 530 |
| 088 | _ | _ | |a arXiv:1905.07166 |2 arXiv |
| 100 | 1 | _ | |a Yachmenev, Andrey |0 P:(DE-H253)PIP1031546 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Field-Induced Diastereomers for Chiral Separation |
| 260 | _ | _ | |c 2019 |
| 336 | 7 | _ | |a Preprint |b preprint |m preprint |0 PUB:(DE-HGF)25 |s 1720599779_2074473 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a WORKING_PAPER |2 ORCID |
| 336 | 7 | _ | |a Electronic Article |0 28 |2 EndNote |
| 336 | 7 | _ | |a preprint |2 DRIVER |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a Output Types/Working Paper |2 DataCite |
| 520 | _ | _ | |a A novel approach for the state-specific enantiomeric enrichment and the spatial separation of enantiomers is presented. Our scheme utilizes techniques from strong-field laser physics, specifically an optical centrifuge in conjunction with a static electric field, to create a chiral field with defined handedness. Molecular enantiomers experience unique rotational excitation dynamics and this can be exploited to spatially separate the enantiomers using electrostatic deflection. Notably, the rotational-state-specific enantiomeric enhancement and its handedness is fully controllable. To explain these effects, we introduce the conceptual framework of $field\text{-}induced~diastereomers$ of a chiral molecule and perform robust quantum mechanical simulations on the prototypical chiral molecule propylene oxide (C$_3$H$_6$O), for which ensembles with an enantiomeric excess of up to $30~\%$ were obtained. |
| 536 | _ | _ | |a 631 - Matter – Dynamics, Mechanisms and Control (POF4-631) |0 G:(DE-HGF)POF4-631 |c POF4-631 |f POF IV |x 0 |
| 536 | _ | _ | |a Ex-Net-0002-Phase2-3 - Advanced Imaging of Matter: Structure, Dynamics and Control on the Atomic Scale - AIM (2018_Ex-Net-0002-Phase2-3) |0 G:(DE-HGF)2018_Ex-Net-0002-Phase2-3 |c 2018_Ex-Net-0002-Phase2-3 |x 1 |
| 536 | _ | _ | |a COMOTION - Controlling the Motion of Complex Molecules and Particles (614507) |0 G:(EU-Grant)614507 |c 614507 |f ERC-2013-CoG |x 2 |
| 536 | _ | _ | |a DFG project 281310165 - Abbildung chemischer Dynamik mittels laserinduzierter Elektronenbeugung im Molekülkoordinatensystem (281310165) |0 G:(GEPRIS)281310165 |c 281310165 |x 3 |
| 536 | _ | _ | |a DFG project 390715994 - EXC 2056: CUI: Advanced Imaging of Matter (390715994) |0 G:(GEPRIS)390715994 |c 390715994 |x 4 |
| 536 | _ | _ | |a DFG project 194651731 - EXC 1074: Hamburger Zentrum für ultraschnelle Beobachtung (CUI): Struktur, Dynamik und Kontrolle von Materie auf atomarer Skala (194651731) |0 G:(GEPRIS)194651731 |c 194651731 |x 5 |
| 588 | _ | _ | |a Dataset connected to DataCite |
| 693 | _ | _ | |0 EXP:(DE-MLZ)NOSPEC-20140101 |5 EXP:(DE-MLZ)NOSPEC-20140101 |e No specific instrument |x 0 |
| 700 | 1 | _ | |a Onvlee, Jolijn |0 P:(DE-H253)PIP1032788 |b 1 |
| 700 | 1 | _ | |a Zak, Emil |0 P:(DE-H253)PIP1088359 |b 2 |
| 700 | 1 | _ | |a Owens, Alec |0 P:(DE-H253)PIP1008016 |b 3 |
| 700 | 1 | _ | |a Küpper, Jochen |0 P:(DE-H253)PIP1012175 |b 4 |
| 856 | 4 | _ | |u https://bib-pubdb1.desy.de/record/611712/files/1905.07166v1.pdf |y Restricted |
| 856 | 4 | _ | |u https://bib-pubdb1.desy.de/record/611712/files/1905.07166v1.pdf?subformat=pdfa |x pdfa |y Restricted |
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| 910 | 1 | _ | |a External Institute |0 I:(DE-HGF)0 |k Extern |b 1 |6 P:(DE-H253)PIP1032788 |
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| 913 | 1 | _ | |a DE-HGF |b Forschungsbereich Materie |l Von Materie zu Materialien und Leben |1 G:(DE-HGF)POF4-630 |0 G:(DE-HGF)POF4-631 |3 G:(DE-HGF)POF4 |2 G:(DE-HGF)POF4-600 |4 G:(DE-HGF)POF |v Matter – Dynamics, Mechanisms and Control |x 0 |
| 915 | _ | _ | |a Published |0 StatID:(DE-HGF)0580 |2 StatID |
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| 920 | 1 | _ | |0 I:(DE-H253)UNI_EXP-20120731 |k UNI/EXP |l Uni Hamburg / Experimentalphysik |x 2 |
| 980 | _ | _ | |a preprint |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a I:(DE-H253)FS-CFEL-CMI-20220405 |
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| 980 | _ | _ | |a UNRESTRICTED |
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