% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Yachmenev:611712,
      author       = {Yachmenev, Andrey and Onvlee, Jolijn and Zak, Emil and
                      Owens, Alec and Küpper, Jochen},
      title        = {{F}ield-{I}nduced {D}iastereomers for {C}hiral
                      {S}eparation},
      reportid     = {PUBDB-2024-05026, arXiv:1905.07166},
      year         = {2019},
      abstract     = {A novel approach for the state-specific enantiomeric
                      enrichment and the spatial separation of enantiomers is
                      presented. Our scheme utilizes techniques from strong-field
                      laser physics, specifically an optical centrifuge in
                      conjunction with a static electric field, to create a chiral
                      field with defined handedness. Molecular enantiomers
                      experience unique rotational excitation dynamics and this
                      can be exploited to spatially separate the enantiomers using
                      electrostatic deflection. Notably, the
                      rotational-state-specific enantiomeric enhancement and its
                      handedness is fully controllable. To explain these effects,
                      we introduce the conceptual framework of
                      $field\text{-}induced~diastereomers$ of a chiral molecule
                      and perform robust quantum mechanical simulations on the
                      prototypical chiral molecule propylene oxide (C$_3$H$_6$O),
                      for which ensembles with an enantiomeric excess of up to
                      $30~\\%$ were obtained.},
      cin          = {FS-CFEL-CMI / UNI/CUI / UNI/EXP},
      ddc          = {530},
      cid          = {I:(DE-H253)FS-CFEL-CMI-20220405 /
                      $I:(DE-H253)UNI_CUI-20121230$ /
                      $I:(DE-H253)UNI_EXP-20120731$},
      pnm          = {631 - Matter – Dynamics, Mechanisms and Control
                      (POF4-631) / Ex-Net-0002-Phase2-3 - Advanced Imaging of
                      Matter: Structure, Dynamics and Control on the Atomic Scale
                      - AIM $(2018_Ex-Net-0002-Phase2-3)$ / COMOTION - Controlling
                      the Motion of Complex Molecules and Particles (614507) / DFG
                      project 281310165 - Abbildung chemischer Dynamik mittels
                      laserinduzierter Elektronenbeugung im
                      Molekülkoordinatensystem (281310165) / DFG project
                      390715994 - EXC 2056: CUI: Advanced Imaging of Matter
                      (390715994) / DFG project 194651731 - EXC 1074: Hamburger
                      Zentrum für ultraschnelle Beobachtung (CUI): Struktur,
                      Dynamik und Kontrolle von Materie auf atomarer Skala
                      (194651731)},
      pid          = {G:(DE-HGF)POF4-631 / $G:(DE-HGF)2018_Ex-Net-0002-Phase2-3$
                      / G:(EU-Grant)614507 / G:(GEPRIS)281310165 /
                      G:(GEPRIS)390715994 / G:(GEPRIS)194651731},
      experiment   = {EXP:(DE-MLZ)NOSPEC-20140101},
      typ          = {PUB:(DE-HGF)25},
      eprint       = {1905.07166},
      howpublished = {arXiv:1905.07166},
      archivePrefix = {arXiv},
      SLACcitation = {$\%\%CITATION$ = $arXiv:1905.07166;\%\%$},
      pubmed       = {pmid:31922822},
      url          = {https://bib-pubdb1.desy.de/record/611712},
}