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@ARTICLE{Piskua:607712,
author = {Piskuła, Zbigniew S. and Darul, Jolanta and Szafran, Maria
and Toliński, Tomasz and Nowicki, Waldemar},
title = {{E}ffects of {N}i doping on structural, magnetic and
catalytic properties of copper ferrite},
journal = {Journal of magnetism and magnetic materials},
volume = {591},
issn = {0304-8853},
address = {Amsterdam},
publisher = {North-Holland Publ. Co.},
reportid = {PUBDB-2024-02015},
pages = {171693},
year = {2024},
note = {(FP7/2007–2013) under Grant agreement no. 226716.},
abstract = {The aim of this work was to obtain information about the
influence of small quantities of Ni$^{2+}$ ion on
thestructural and magnetic properties of the tetragonally
distorted of Cu$_{1-x}$Ni$_x$Fe$_2$O4 series (with x = 0.00,
0.05,0.1, and 0.15 respectively). The tested ferrite system
was synthesized by combustion of citrate–nitrate
precursors.The synchrotron X-ray diffraction measurements
determined the phase transition temperatures (tetragonal
→cubic) of all samples. The change of structures under the
influence of temperature shows a phase transition in
therange of 390 – 400 ◦C for x = 0.00, 330 – 370 ◦C
for x = 0.05, 210 – 330 ◦C for x = 0.1 and 140 – 210
◦C for x= 0.15, respectively. The initial phase transition
temperature decreases linearly with the decreasing c/a ratio
ofthe crystallographic lattice parameters for the
Cu$_{1-x}$Ni$_x$Fe$_2$O$_4$ oxides. Hysteresis measurements
were made todetermine the saturation magnetization (M$_S$)
and coercive field (μ$_0$H$_c$) of the samples. The values
of magneticmoments at room temperature determined from
magnetization measurements are very similar to those
obtainedfrom theoretical x-ray diffraction calculations.
Magnetic moment values per formula unit are estimated to
rangefrom 1.16 μB to 1.5 μB. It was found that the
catalytic activity of N$_2$O decomposition of samples
increases withincreasing nickel content.},
cin = {DOOR ; HAS-User},
ddc = {530},
cid = {I:(DE-H253)HAS-User-20120731},
pnm = {899 - ohne Topic (POF4-899) / FS-Proposal: I-20110697 EC
(I-20110697-EC) / FS-Proposal: I-20100021 EC
(I-20100021-EC)},
pid = {G:(DE-HGF)POF4-899 / G:(DE-H253)I-20110697-EC /
G:(DE-H253)I-20100021-EC},
experiment = {EXP:(DE-H253)D-B2-20150101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:001161997300001},
doi = {10.1016/j.jmmm.2023.171693},
url = {https://bib-pubdb1.desy.de/record/607712},
}