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@ARTICLE{Zenner:607685,
      author       = {Zenner, Johannes and Tran, Kelly and Kang, Liqun and
                      Kinzel, Niklas W. and Werlé, Christophe and DeBeer, Serena
                      and Bordet, Alexis and Leitner, Walter},
      title        = {{S}ynthesis, {C}haracterization, and {C}atalytic
                      {A}pplication of {C}olloidal and {S}upported {M}anganese
                      {N}anoparticles},
      journal      = {Chemistry - a European journal},
      volume       = {30},
      number       = {25},
      issn         = {0947-6539},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {PUBDB-2024-01988},
      pages        = {e202304228},
      year         = {2024},
      abstract     = {Colloidal and supported manganese nanoparticles were
                      synthesized following an organometallic approach and applied
                      in the catalytic transfer hydrogenation (CTH) of aldehydes
                      and ketones. Reaction parameters for the preparation of
                      colloidal nanoparticles (NPs) were optimized to yield small
                      (2–2.5 nm) and well-dispersed NPs. Manganese NPs were
                      further immobilized on an imidazolium-based supported ionic
                      phase (SILP) and characterized to evaluate NP size, metal
                      loading, and oxidation states. Oxidation of the Mn NPs by
                      the support was observed resulting in an average formal
                      oxidation state of +2.5. The MnO$_x$@SILP material showed
                      promising performance in the CTH of aldehydes and ketones
                      using 2-propanol as a hydrogen donor, outperforming
                      previously reported Mn NPs-based CTH catalysts in terms of
                      metal loading-normalized turnover numbers. Interestingly,
                      MnO$_x$@SILP were found to lose activity upon air exposure,
                      which correlates with an additional increase in the average
                      oxidation state of Mn as revealed by X-ray absorption
                      spectroscopic studies.},
      cin          = {DOOR ; HAS-User},
      ddc          = {540},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {6G3 - PETRA III (DESY) (POF4-6G3) / DFG project 390919832 -
                      EXC 2186: Das Fuel Science Center – Adaptive
                      Umwandlungssysteme für erneuerbare Energie- und
                      Kohlenstoffquellen (390919832) / FS-Proposal: I-20211319
                      (I-20211319)},
      pid          = {G:(DE-HGF)POF4-6G3 / G:(GEPRIS)390919832 /
                      G:(DE-H253)I-20211319},
      experiment   = {EXP:(DE-H253)P-P65-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:38415315},
      UT           = {WOS:001183888100001},
      doi          = {10.1002/chem.202304228},
      url          = {https://bib-pubdb1.desy.de/record/607685},
}