% IMPORTANT: The following is UTF-8 encoded. This means that in the presence % of non-ASCII characters, it will not work with BibTeX 0.99 or older. % Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or % “biber”. @ARTICLE{Bloss:607622, author = {Bloss, Dana and Trinter, Florian and Unger, Isaak and Zindel, Christina and Honisch, Carolin and Viehmann, Johannes and Kiefer, Nils and Marder, Lutz and Küstner-Wetekam, Catmarna and Heikura, Emilia and Cederbaum, Lorenz S. and Björneholm, Olle and Hergenhahn, Uwe and Ehresmann, Arno and Hans, Andreas}, title = {{X}-ray radiation damage cycle of solvated inorganic ions}, journal = {Nature Communications}, volume = {15}, number = {1}, issn = {2041-1723}, address = {[London]}, publisher = {Nature Publishing Group UK}, reportid = {PUBDB-2024-01958}, pages = {4594}, year = {2024}, note = {05K19RK2, 2023-04346}, abstract = {X-ray-induced damage is one of the key topics in radiation chemistry. Substantialdamage is attributed to low-energy electrons and radicals emergingfrom direct inner-shell photoionization or produced by subsequent processes.We apply multi-electron coincidence spectroscopy to X-ray-irradiated aqueoussolutions of inorganic ions to investigate the production of low-energyelectrons (LEEs) in a predicted cascade of intermolecular charge- and energytransferprocesses, namely electron-transfer-mediated decay (ETMD) andinteratomic/intermolecular Coulombic decay (ICD). An advanced coincidencetechnique allows us to identify several LEE-producing steps during the decayof 1s vacancies in solvated Mg$^{2+}$ ions, which escaped observation in previousnon-coincident experiments. We provide strong evidence for the predictedrecovering of the ion’s initial state. In natural environments the recovering ofthe ion’s initial state is expected to cause inorganic ions to be radiationdamagehot spots, repeatedly producing destructive particles under continuousirradiation.}, cin = {DOOR ; HAS-User}, ddc = {500}, cid = {I:(DE-H253)HAS-User-20120731}, pnm = {6G3 - PETRA III (DESY) (POF4-6G3) / FS-Proposal: I-20210172 (I-20210172) / SWEDEN-DESY - SWEDEN-DESY Collaboration $(2020_Join2-SWEDEN-DESY)$ / 05K22RK1 - Verbundprojekt 05K2022 - TRANSALP: Zeit- $\&$ winkelaufgelöste Spektroskopie an Proben in der flüssigen Phase. Teilprojekt 2: Aufbau Liquid Jet und KI-basierte Datenanalyse. (BMBF-05K22RK1) / SFB 1319 T01 - Förderung des Wissenschaftsverständnisses in Schulen durch den Transfer von ELCH-Aktivitäten (T01) (491565994) / DFG project 509471550 - Dynamik photoionisations-induzierter Prozesse in laser-präparierten Molekülen in der Gasphase und der wässrigen Phase (509471550) / $ETMD_ICEC$ - Efficient pathways to neutralization and radical production enabled by environment (692657)}, pid = {G:(DE-HGF)POF4-6G3 / G:(DE-H253)I-20210172 / $G:(DE-HGF)2020_Join2-SWEDEN-DESY$ / G:(DE-Ds200)BMBF-05K22RK1 / G:(GEPRIS)491565994 / G:(GEPRIS)509471550 / G:(EU-Grant)692657}, experiment = {EXP:(DE-H253)P-P04-20150101}, typ = {PUB:(DE-HGF)16}, pubmed = {pmid:38816362}, UT = {WOS:001236316700008}, doi = {10.1038/s41467-024-48687-2}, url = {https://bib-pubdb1.desy.de/record/607622}, }