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@ARTICLE{Mullins:607376,
author = {Mullins, Terry and Karamatskos, Evangelos Thomas and Wiese,
Joss and Onvlee, Jolijn and Rouzée, Arnaud and Yachmenev,
Andrey and Trippel, Sebastian and Küpper, Jochen},
title = {{P}icosecond pulse-shaping for strong three-dimensional
field-free alignment of generic asymmetric-top molecules},
reportid = {PUBDB-2024-01858, arXiv:2009.08157},
year = {2022},
abstract = {Fixing molecules in space is a crucial step for the imaging
of molecular structure and dynamics. Here, we demonstrate
three-dimensional (3D) field-free alignment of the
prototypical asymmetric top molecule indole using
elliptically polarized, shaped, off-resonant laser pulses. A
truncated laser pulse is produced using a combination of
extreme linear chirping and controlled phase and amplitude
shaping using a spatial-light-modulator (SLM) based pulse
shaper of a broadband laser pulse. The angular confinement
is detected through velocity-map imaging of H$^+$ and
C$^{2+}$ fragments resulting from strong-field ionization
and Coulomb explosion of the aligned molecules by intense
femtosecond laser pulses. The achieved three-dimensional
alignment is characterized by comparing the result of
ion-velocity-map measurements for different alignment
directions and for different times during and after the
alignment laser pulse to accurate computational results. The
achieved strong three-dimensional field-free alignment of
$\langle \cos^{2}\delta \rangle=0.89$ demonstrates the
feasibility of both, strong three-dimensional alignment of
generic complex molecules and its quantitative
characterization.},
cin = {FS-CFEL-CMI / UNI/CUI / UNI/EXP},
cid = {I:(DE-H253)FS-CFEL-CMI-20220405 /
$I:(DE-H253)UNI_CUI-20121230$ /
$I:(DE-H253)UNI_EXP-20120731$},
pnm = {631 - Matter – Dynamics, Mechanisms and Control
(POF4-631) / MEDEA - Molecular Electron Dynamics
investigated by IntensE Fields and Attosecond Pulses
(641789) / DFG project 390715994 - EXC 2056: CUI: Advanced
Imaging of Matter (390715994) / COMOTION - Controlling the
Motion of Complex Molecules and Particles (614507)},
pid = {G:(DE-HGF)POF4-631 / G:(EU-Grant)641789 /
G:(GEPRIS)390715994 / G:(EU-Grant)614507},
experiment = {EXP:(DE-H253)CFEL-Exp-20150101},
typ = {PUB:(DE-HGF)25},
eprint = {2009.08157},
howpublished = {arXiv:2009.08157},
archivePrefix = {arXiv},
SLACcitation = {$\%\%CITATION$ = $arXiv:2009.08157;\%\%$},
url = {https://bib-pubdb1.desy.de/record/607376},
}