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000607359 0247_ $$2arXiv$$aarXiv:2308.08006
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000607359 088__ $$2arXiv$$aarXiv:2308.08006
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000607359 1001_ $$0P:(DE-H253)PIP1097162$$aVinklarek, Ivo$$b0$$udesy
000607359 245__ $$aReaction Pathways of Water Dimer Following Single Ionization
000607359 260__ $$c2024
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000607359 520__ $$aWater dimer $(\text{H}_2\text{O})_2$ -- a vital component of the earth's atmosphere -- is an important prototypical hydrogen-bonded system. It provides direct insight into fundamental chemical and biochemical processes, e.g., proton transfer and ionic supramolecular dynamics occurring in astro- and atmospheric chemistry. Exploiting a purified molecular beam of water dimer and multi-mass ion imaging, we report the simultaneous detection of all generated ion products of $(\text{H}_2\text{O})^{+}_2$-fragmentation following single ionization. Detailed information about ion yields and reaction energetics of 13 ion-radical pathways, 6 of which are new, of $(\text{H}_2\text{O})^{+}_2$ are presented, including strong ${}^{18}\text{O}$-isotope effects.
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000607359 536__ $$0G:(DE-HGF)2020_HIRS-0018$$aHIRS-0018 - Helmholtz-Lund International School - Intelligent instrumentation for exploring matter at different time and length scales (HELIOS) (2020_HIRS-0018)$$c2020_HIRS-0018$$x1
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000607359 7001_ $$0P:(DE-H253)PIP1013244$$aBromberger, Hubertus$$b1$$udesy
000607359 7001_ $$0P:(DE-H253)PIP1097874$$aVadassery, Nidin$$b2$$udesy
000607359 7001_ $$0P:(DE-H253)PIP1091789$$aJin, Wuwei$$b3$$udesy
000607359 7001_ $$0P:(DE-H253)PIP1012175$$aKüpper, Jochen$$b4$$eCorresponding author$$udesy
000607359 7001_ $$0P:(DE-H253)PIP1013309$$aTrippel, Sebastian$$b5$$eCorresponding author$$udesy
000607359 8564_ $$uhttps://arxiv.org/abs/2308.08006
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