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@ARTICLE{Du:605553,
      author       = {Du, Jingwei and Zhao, Yirong and Chu, Xingyuan and Wang,
                      Gang and Neumann, Christof and Xu, Hao and Li, Xiaodong and
                      Löffler, Markus and Lu, Qiongqiong and Zhang, Jiaxu and Li,
                      Dongqi and Zou, Jianxin and Mikhailova, Daria and Turchanin,
                      Andrey and Feng, Xinliang and Yu, Minghao},
      title        = {{A} {H}igh‐{E}nergy {T}ellurium {R}edox‐{A}mphoteric
                      {C}onversion {C}athode {C}hemistry for {A}queous {Z}inc
                      {B}atteries},
      journal      = {Advanced materials},
      volume       = {36},
      number       = {19},
      issn         = {0935-9648},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {PUBDB-2024-01504},
      pages        = {2313621},
      year         = {2024},
      abstract     = {Rechargeable aqueous zinc batteries are potential
                      candidates for sustainable energy storage systems at a grid
                      scale, owing to their high safety and low cost. However, the
                      existing cathode chemistries exhibit restricted energy
                      density, which hinders their extensive applications. Here, a
                      tellurium redox-amphoteric conversion cathode chemistry is
                      presented for aqueous zinc batteries, which delivers a
                      specific capacity of 1223.9 mAh gTe$^{−1}$ and a high
                      energy density of 1028.0 Wh kgTe$^{−1}$. A highly
                      concentrated electrolyte (30 mol kg$^{−1}$ ZnCl$_2$) is
                      revealed crucial for initiating the Te redox-amphoteric
                      conversion as it suppresses the H$_2$O reactivity and
                      inhibits undesirable hydrolysis of the Te$^{4+}$ product. By
                      carrying out multiple operando/ex situ characterizations,
                      the reversible six-electron Te$^{2−}$/Te$^0$/Te$^{4+}$
                      conversion with TeCl$_4$ is identified as the fully charged
                      product and ZnTe as the fully discharged product. This
                      finding not only enriches the conversion-type battery
                      chemistries but also establishes a critical step in
                      exploring redox-amphoteric materials for aqueous zinc
                      batteries and beyond.},
      cin          = {DOOR ; HAS-User},
      ddc          = {660},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {6G3 - PETRA III (DESY) (POF4-6G3) / DFG project
                      G:(GEPRIS)417590517 - SFB 1415: Chemie der synthetischen
                      zweidimensionalen Materialien (417590517)},
      pid          = {G:(DE-HGF)POF4-6G3 / G:(GEPRIS)417590517},
      experiment   = {EXP:(DE-H253)P-P65-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:38316395},
      UT           = {WOS:001160308100001},
      doi          = {10.1002/adma.202313621},
      url          = {https://bib-pubdb1.desy.de/record/605553},
}