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000605553 1001_ $$0P:(DE-H253)PIP1098080$$aDu, Jingwei$$b0
000605553 245__ $$aA High‐Energy Tellurium Redox‐Amphoteric Conversion Cathode Chemistry for Aqueous Zinc Batteries
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000605553 520__ $$aRechargeable aqueous zinc batteries are potential candidates for sustainable energy storage systems at a grid scale, owing to their high safety and low cost. However, the existing cathode chemistries exhibit restricted energy density, which hinders their extensive applications. Here, a tellurium redox-amphoteric conversion cathode chemistry is presented for aqueous zinc batteries, which delivers a specific capacity of 1223.9 mAh gTe$^{−1}$ and a high energy density of 1028.0 Wh kgTe$^{−1}$. A highly concentrated electrolyte (30 mol kg$^{−1}$ ZnCl$_2$) is revealed crucial for initiating the Te redox-amphoteric conversion as it suppresses the H$_2$O reactivity and inhibits undesirable hydrolysis of the Te$^{4+}$ product. By carrying out multiple operando/ex situ characterizations, the reversible six-electron Te$^{2−}$/Te$^0$/Te$^{4+}$ conversion with TeCl$_4$ is identified as the fully charged product and ZnTe as the fully discharged product. This finding not only enriches the conversion-type battery chemistries but also establishes a critical step in exploring redox-amphoteric materials for aqueous zinc batteries and beyond.
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000605553 7001_ $$aZhao, Yirong$$b1
000605553 7001_ $$0P:(DE-H253)PIP1101476$$aChu, Xingyuan$$b2
000605553 7001_ $$0P:(DE-H253)PIP1008694$$aWang, Gang$$b3
000605553 7001_ $$aNeumann, Christof$$b4
000605553 7001_ $$0P:(DE-H253)PIP1107337$$aXu, Hao$$b5
000605553 7001_ $$0P:(DE-H253)PIP1080044$$aLi, Xiaodong$$b6
000605553 7001_ $$aLöffler, Markus$$b7
000605553 7001_ $$0P:(DE-H253)PIP1090398$$aLu, Qiongqiong$$b8
000605553 7001_ $$aZhang, Jiaxu$$b9
000605553 7001_ $$0P:(DE-H253)PIP1092232$$aLi, Dongqi$$b10
000605553 7001_ $$aZou, Jianxin$$b11
000605553 7001_ $$0P:(DE-H253)PIP1008118$$aMikhailova, Daria$$b12
000605553 7001_ $$aTurchanin, Andrey$$b13
000605553 7001_ $$0P:(DE-H253)PIP1081776$$aFeng, Xinliang$$b14$$eCorresponding author
000605553 7001_ $$0P:(DE-H253)PIP1083931$$aYu, Minghao$$b15$$eCorresponding author
000605553 773__ $$0PERI:(DE-600)1474949-X$$a10.1002/adma.202313621$$gp. 2313621$$n19$$p2313621$$tAdvanced materials$$v36$$x0935-9648$$y2024
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