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@ARTICLE{Frost:605543,
author = {Frost, Mungo and McWilliams, R. Stewart and Bykova, Elena
and Bykov, Maxim and Husband, Rachel J. and
Andriambariarijaona, Leon M. and Khandarkhaeva, Saiana and
Massani, Bernhard and Appel, Karen and Baehtz, Carsten and
Ball, Orianna B. and Cerantola, Valerio and Chariton, Stella
and Choi, Jinhyuk and Cynn, Hyunchae and Duff, Matthew J.
and Dwivedi, Anand and Edmund, Eric and Fiquet, Guillaume
and Graafsma, Heinz and Hwang, Huijeong and Jaisle, Nicolas
and Kim, Jaeyong and Konôpková, Zuzana and Laurus, Torsten
and Lee, Yongjae and Liermann, Hanns-Peter and McHardy,
James D. and McMahon, Malcolm I. and Morard, Guillaume and
Nakatsutsumi, Motoaki and Nguyen, Lan Anh and Ninet, Sandra
and Prakapenka, Vitali B. and Prescher, Clemens and Redmer,
Ronald and Stern, Stephan and Strohm, Cornelius and
Sztuk-Dambietz, Jolanta and Turcato, Monica and Wu, Zhongyan
and Glenzer, Siegfried H. and Goncharov, Alexander F.},
title = {{D}iamond precipitation dynamics from hydrocarbons at icy
planet interior conditions},
journal = {Nature astronomy},
volume = {8},
number = {2},
issn = {2397-3366},
address = {London},
publisher = {Nature Publishing Group},
reportid = {PUBDB-2024-01494},
pages = {174-181},
year = {2024},
abstract = {The pressure and temperature conditions at which
precipitation of diamond occurs from hydrocarbon mixtures is
important for modelling the interior dynamics of icy
planets. However, there is substantial disagreement from
laboratory experiments, with those using dynamic compression
techniques finding much more extreme conditions are required
than in static compression. Here we report the time-resolved
observation of diamond formation from statically compressed
polystyrene, (C$_8$H$_8$)$_n$, heated using the 4.5 MHz
X-ray pulse trains at the European X-ray Free Electron Laser
facility. Diamond formation is observed above 2,500 K from
19 GPa to 27 GPa, conditions representative of
Uranus’s and Neptune’s shallow interiors, on 30 μs to
40 μs timescales. This is much slower than may be
observed during the ∼10 ns duration of typical dynamic
compression experiments, revealing reaction kinetics to be
the reason for the discrepancy. Reduced pressure and
temperature conditions for diamond formation has
implications for icy planetary interiors, where diamond
subduction leads to heating and could drive convection in
the conductive ice layer that has a role in their magnetic
fields.},
cin = {DOOR ; HAS-User / FS-HIBEF / $XFEL_E1_HED$ / CFEL-DRD /
$XFEL_DO_DD_DET$},
ddc = {520},
cid = {I:(DE-H253)HAS-User-20120731 / I:(DE-H253)FS-HIBEF-20240110
/ $I:(DE-H253)XFEL_E1_HED-20210408$ /
I:(DE-H253)CFEL-DRD-20160910 /
$I:(DE-H253)XFEL_DO_DD_DET-20210408$},
pnm = {631 - Matter – Dynamics, Mechanisms and Control
(POF4-631) / 6G3 - PETRA III (DESY) (POF4-6G3)},
pid = {G:(DE-HGF)POF4-631 / G:(DE-HGF)POF4-6G3},
experiment = {EXP:(DE-H253)P-P02.2-20150101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:001138168700001},
doi = {10.1038/s41550-023-02147-x},
url = {https://bib-pubdb1.desy.de/record/605543},
}