001     605154
005     20250416150425.0
024 7 _ |a arXiv:2408.01125
|2 arXiv
024 7 _ |a inspire:2814159
|2 inspire
024 7 _ |a 10.3204/PUBDB-2024-01328
|2 datacite_doi
037 _ _ |a PUBDB-2024-01328
041 _ _ |a English
088 _ _ |a arXiv:2408.01125
|2 arXiv
100 1 _ |a Thesing, Linda
|0 P:(DE-HGF)0
|b 0
245 _ _ |a Molecular influence on nuclear-quadrupole coupling effects in laser induced alignment
260 _ _ |c 2024
336 7 _ |a Preprint
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336 7 _ |a Electronic Article
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336 7 _ |a preprint
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336 7 _ |a ARTICLE
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336 7 _ |a Output Types/Working Paper
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520 _ _ |a We studied the effect of nuclear-quadrupole interactions on the field-free impulsive alignment of different asymmetric-top molecules. Our analysis is focused on the influence of the hyperfine- and rotational-energy-level structures. These depend on the number of nuclear spins, the rotational constants, and the symmetry of the tensors involved in the nuclear spin and external field interactions. Comparing the prototypical large-nuclear- spin molecules iodobenzene, 1,2-diiodobenzene, 1,3-diiodobenzene, and 2,5-diiodobenzonitrile, we demonstrate that the magnitude of the hyperfine splittings compared to the rotational-energy splittings plays a crucial role in the spin-rotational dynamics after the laser pulse. Moreover, we point out that the impact of the quadrupole coupling on the rotational dynamics decreases when highly excited rotational states dominate the dynamics.
536 _ _ |a 631 - Matter – Dynamics, Mechanisms and Control (POF4-631)
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536 _ _ |a DFG project G:(GEPRIS)255652344 - SPP 1840: Quantum Dynamics in Tailored Intense Fields (QUTIF) (255652344)
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536 _ _ |a DFG project G:(GEPRIS)194651731 - EXC 1074: Hamburger Zentrum für ultraschnelle Beobachtung (CUI): Struktur, Dynamik und Kontrolle von Materie auf atomarer Skala (194651731)
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536 _ _ |a AIM, DFG project G:(GEPRIS)390715994 - EXC 2056: CUI: Advanced Imaging of Matter (390715994)
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693 _ _ |0 EXP:(DE-MLZ)NOSPEC-20140101
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700 1 _ |a Yachmenev, Andrey
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700 1 _ |a González-Férez, Rosario
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700 1 _ |a Küpper, Jochen
|0 P:(DE-H253)PIP1012175
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856 4 _ |y OpenAccess
|u https://bib-pubdb1.desy.de/record/605154/files/2408.01125v1.pdf
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910 1 _ |a Deutsches Elektronen-Synchrotron
|0 I:(DE-588b)2008985-5
|k DESY
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|6 P:(DE-H253)PIP1031546
910 1 _ |a Centre for Free-Electron Laser Science
|0 I:(DE-H253)_CFEL-20120731
|k CFEL
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910 1 _ |a Deutsches Elektronen-Synchrotron
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910 1 _ |a Centre for Free-Electron Laser Science
|0 I:(DE-H253)_CFEL-20120731
|k CFEL
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910 1 _ |a European XFEL
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913 1 _ |a DE-HGF
|b Forschungsbereich Materie
|l Von Materie zu Materialien und Leben
|1 G:(DE-HGF)POF4-630
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|v Matter – Dynamics, Mechanisms and Control
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914 1 _ |y 2024
915 _ _ |a OpenAccess
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915 _ _ |a Creative Commons Attribution-NonCommercial-NoDerivs CC BY-NC-ND 4.0
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915 _ _ |a Published
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920 1 _ |0 I:(DE-H253)FS-CFEL-CMI-20220405
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920 1 _ |0 I:(DE-H253)UNI_CUI-20121230
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920 1 _ |0 I:(DE-H253)UNI_EXP-20120731
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|l Uni Hamburg / Experimentalphysik
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980 _ _ |a preprint
980 _ _ |a VDB
980 _ _ |a UNRESTRICTED
980 _ _ |a I:(DE-H253)FS-CFEL-CMI-20220405
980 _ _ |a I:(DE-H253)UNI_CUI-20121230
980 _ _ |a I:(DE-H253)UNI_EXP-20120731
980 1 _ |a FullTexts


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