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@ARTICLE{Naumova:604021,
      author       = {Naumova, Maria and paveliuc, gheorghe and Biednov, Mykola
                      and Kubicek, Katharina and Kalinko, Aleksandr and Meng, Jie
                      and Liang, Mingli and Rahaman, Ahibur and Abdellah, Mohamed
                      and Checchia, Stefano and Alves Lima, Frederico and Zalden,
                      Peter and Gawelda, Wojciech and Bressler, Christian and
                      Geng, Huifang and Lin, Weihua and Liu, Yan and Zhao, Qian
                      and Pan, Qinying and Akter, Marufa and Kong, Qingyu and
                      Retegan, Marius and Gosztola, David and Papai, Matyas and
                      Khakhulin, Dmitry and Lawson Daku, Latévi and Zheng, Kaibo
                      and Canton, Sophie},
      title        = {{N}onadiabatic charge-transfer within photoexcited nickel
                      porphyrins},
      journal      = {The journal of physical chemistry letters},
      volume       = {15},
      number       = {13},
      issn         = {1948-7185},
      address      = {Washington, DC},
      publisher    = {ACS},
      reportid     = {PUBDB-2024-00986},
      pages        = {3627-3638},
      year         = {2024},
      note         = {This publication is licensed under CC-BY 4.0.This work
                      received funding fromthe VILLUM FONDEN (VIL50350), and the
                      SwedishResearch Council No. 2021-05319 (KZ). This work
                      receivedfunding from the Hungarian National Research,
                      Developmentand Innovation Fund under Grant Nos. NKFIH FK
                      145967(MP) and TKP2021-NVA-04 (MP). KK gratefully
                      acknowl-edges funding by the DFG within the program
                      “Sachbeihilfe”project ID 497431350 (KU 4184/1-1). CB and
                      KK acknowl-edge support by the Deutsche
                      Forschungsgemeinschaft (DFG)via the Cluster of Excellence
                      ‘Advanced Imaging of Matter’,EXC 2056, Project ID
                      390715994, and via SFB925 ID170620586 (TP A4). WG
                      acknowledges funding from SpanishMIU through “Ayudas
                      Beatriz Galindo” (BEAGAL18/00092),Comunidad de Madrid and
                      Universidad Autónoma de Madridthrough “Proyecto de I+D
                      para Investigadores del ProgramaBeatriz Galindo”
                      (SI2/PBG/2020-00003), Spanish MICIUthrough Proyecto de I+D+i
                      2019 (PID2019-108678GB-I00),and IMDEA-Nanociencia support
                      from the Severo OchoaProgramme for Centers of Excellence in
                      $R\&D$ (MINECO,grant CEX2020-001039-S). WG further
                      acknowledges partialsupport from the National Science Centre
                      in Poland underSONATA BIS 6 Grant 2016/22/E/ST4/00543 and
                      thesupport to access the European XFEL under a grant of
                      thePolish Ministry of Education and Science - decision no.
                      2022/WK/13. DG acknowledges support from the Center
                      forNanoscale Materials, a U.S. Department of Energy Office
                      ofScience User Facility, supported by the U.S. DOE, Office
                      ofBasic Energy Sciences, under Contract No.
                      DE-AC02-06CH11357. MP acknowledges support from the János
                      BolyaiScholarship of the Hungarian Academy of Sciences.},
      abstract     = {Metalloporphyrins with open d-shell ions can drive
                      biochemical energy cycles.However, their utilization in
                      photoconversion is hampered by rapid deactivation.
                      Mappingthe relaxation pathways is essential for elaborating
                      strategies that can favorably alter thecharge dynamics
                      through chemical design and photoexcitation conditions.
                      Here, we combinetransient optical absorption spectroscopy
                      and transient X-ray emission spectroscopy withfemtosecond
                      resolution to probe directly the coupled electronic and spin
                      dynamics within aphotoexcited nickel porphyrin in solution.
                      Measurements and calculations reveal that a statewith
                      charge-transfer character mediates the formation of the
                      thermalized excited state,thereby advancing the description
                      of the photocycle for this important representativemolecule.
                      More generally, establishing that intramolecular
                      charge-transfer steps play a role inthe photoinduced
                      dynamics of metalloporphyrins with open d-shell sets a
                      conceptual groundfor their development as building blocks
                      capable of boosting nonadiabatic photoconversionin
                      functional architectures through “hot” charge transfer
                      down to the attosecond time scale.},
      cin          = {FS-PETRA-S / XFEL-User / $XFEL_E1_FXE$},
      ddc          = {530},
      cid          = {I:(DE-H253)FS-PETRA-S-20210408 /
                      I:(DE-H253)XFEL-User-20170713 /
                      $I:(DE-H253)XFEL_E1_FXE-20210408$},
      pnm          = {631 - Matter – Dynamics, Mechanisms and Control
                      (POF4-631) / DFG project 194651731 - EXC 1074: Hamburger
                      Zentrum für ultraschnelle Beobachtung (CUI): Struktur,
                      Dynamik und Kontrolle von Materie auf atomarer Skala
                      (194651731) / DFG project 390715994 - EXC 2056: CUI:
                      Advanced Imaging of Matter (390715994)},
      pid          = {G:(DE-HGF)POF4-631 / G:(GEPRIS)194651731 /
                      G:(GEPRIS)390715994},
      experiment   = {EXP:(DE-H253)XFEL-FXE-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {38530393},
      UT           = {WOS:001191209200001},
      doi          = {10.1021/acs.jpclett.4c00375},
      url          = {https://bib-pubdb1.desy.de/record/604021},
}