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| 001 | 603202 | ||
| 005 | 20250715170848.0 | ||
| 024 | 7 | _ | |a 10.1021/acs.inorgchem.3c04433 |2 doi |
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| 100 | 1 | _ | |a Ambach, Sebastian |0 P:(DE-H253)PIP1087547 |b 0 |
| 245 | _ | _ | |a Nitride Synthesis under High-Pressure, High-Temperature Conditions: Unprecedented In Situ Insight into the Reaction |
| 260 | _ | _ | |a Washington, DC |c 2024 |b American Chemical Society |
| 336 | 7 | _ | |a article |2 DRIVER |
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| 520 | _ | _ | |a High-pressure, high-temperature (HP/HT) syntheses are essential for modern high-performance materials. Phosphorus nitride, nitridophosphate, and more generally nitride syntheses benefit greatly from HP/HT conditions. In this contribution, we present the first systematic in situ investigation of a nitridophosphate HP/HT synthesis using the reaction of zinc nitride Zn$_3$N$_2$ and phosphorus(V) nitride P$_3$N$_5$ to the nitride semiconductor Zn$_2$PN$_3$ as a case study. At a pressure of 8 GPa and temperatures up to 1300 °C, the reaction was monitored by energy-dispersive powder X-ray diffraction (ED-PXRD) in a large-volume press at beamline P61B at DESY. The experiments investigate the general behavior of the starting materials under extreme conditions and give insight into the reaction. During cold compression and subsequent heating, the starting materials remain crystalline above their ambient-pressure decomposition points, until a sufficient minimum temperature is reached and the reaction starts. The reaction proceeds via ion diffusion at grain boundaries with an exponential decay in the reaction rate. Raising the temperature above the minimum required value quickly completes the reaction and initiates single-crystal growth. After cooling and decompression, which did not influence the resulting product, the recovered sample was analyzed by energy-dispersive X-ray (EDX) spectroscopy. |
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| 542 | _ | _ | |i 2024-02-07 |2 Crossref |u https://doi.org/10.15223/policy-029 |
| 542 | _ | _ | |i 2024-02-07 |2 Crossref |u https://doi.org/10.15223/policy-037 |
| 542 | _ | _ | |i 2024-02-07 |2 Crossref |u https://doi.org/10.15223/policy-045 |
| 588 | _ | _ | |a Dataset connected to CrossRef, Journals: bib-pubdb1.desy.de |
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| 700 | 1 | _ | |a Pritzl, Reinhard M. |0 P:(DE-H253)PIP1092396 |b 1 |
| 700 | 1 | _ | |a Bhat, Shrikant |0 P:(DE-H253)PIP1015084 |b 2 |
| 700 | 1 | _ | |a Farla, Robert |0 P:(DE-H253)PIP1080589 |b 3 |
| 700 | 1 | _ | |a Schnick, Wolfgang |0 P:(DE-H253)PIP1011040 |b 4 |e Corresponding author |
| 773 | 1 | 8 | |a 10.1021/acs.inorgchem.3c04433 |b American Chemical Society (ACS) |d 2024-02-07 |n 7 |p 3535-3543 |3 journal-article |2 Crossref |t Inorganic Chemistry |v 63 |y 2024 |x 0020-1669 |
| 773 | _ | _ | |a 10.1021/acs.inorgchem.3c04433 |g Vol. 63, no. 7, p. 3535 - 3543 |0 PERI:(DE-600)1484438-2 |n 7 |p 3535-3543 |t Inorganic chemistry |v 63 |y 2024 |x 0020-1669 |
| 856 | 4 | _ | |u https://bib-pubdb1.desy.de/record/603202/files/Published%20article.pdf |
| 856 | 4 | _ | |y Published on 2024-02-07. Available in OpenAccess from 2025-02-07. |u https://bib-pubdb1.desy.de/record/603202/files/document.pdf |
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| 856 | 4 | _ | |y Published on 2024-02-07. Available in OpenAccess from 2025-02-07. |x pdfa |u https://bib-pubdb1.desy.de/record/603202/files/document.pdf?subformat=pdfa |
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