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@ARTICLE{Ambach:603202,
      author       = {Ambach, Sebastian and Pritzl, Reinhard M. and Bhat,
                      Shrikant and Farla, Robert and Schnick, Wolfgang},
      title        = {{N}itride {S}ynthesis under {H}igh-{P}ressure,
                      {H}igh-{T}emperature {C}onditions: {U}nprecedented {I}n
                      {S}itu {I}nsight into the {R}eaction},
      journal      = {Inorganic chemistry},
      volume       = {63},
      number       = {7},
      issn         = {0020-1669},
      address      = {Washington, DC},
      publisher    = {American Chemical Society},
      reportid     = {PUBDB-2024-00836},
      pages        = {3535-3543},
      year         = {2024},
      abstract     = {High-pressure, high-temperature (HP/HT) syntheses are
                      essential for modern high-performance materials. Phosphorus
                      nitride, nitridophosphate, and more generally nitride
                      syntheses benefit greatly from HP/HT conditions. In this
                      contribution, we present the first systematic in situ
                      investigation of a nitridophosphate HP/HT synthesis using
                      the reaction of zinc nitride Zn$_3$N$_2$ and phosphorus(V)
                      nitride P$_3$N$_5$ to the nitride semiconductor Zn$_2$PN$_3$
                      as a case study. At a pressure of 8 GPa and temperatures up
                      to 1300 °C, the reaction was monitored by energy-dispersive
                      powder X-ray diffraction (ED-PXRD) in a large-volume press
                      at beamline P61B at DESY. The experiments investigate the
                      general behavior of the starting materials under extreme
                      conditions and give insight into the reaction. During cold
                      compression and subsequent heating, the starting materials
                      remain crystalline above their ambient-pressure
                      decomposition points, until a sufficient minimum temperature
                      is reached and the reaction starts. The reaction proceeds
                      via ion diffusion at grain boundaries with an exponential
                      decay in the reaction rate. Raising the temperature above
                      the minimum required value quickly completes the reaction
                      and initiates single-crystal growth. After cooling and
                      decompression, which did not influence the resulting
                      product, the recovered sample was analyzed by
                      energy-dispersive X-ray (EDX) spectroscopy.},
      cin          = {DOOR ; HAS-User / FS-PETRA-D},
      ddc          = {540},
      cid          = {I:(DE-H253)HAS-User-20120731 /
                      I:(DE-H253)FS-PETRA-D-20210408},
      pnm          = {632 - Materials – Quantum, Complex and Functional
                      Materials (POF4-632) / 6G3 - PETRA III (DESY) (POF4-6G3)},
      pid          = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G3},
      experiment   = {EXP:(DE-H253)P-P61.2-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {38324917},
      UT           = {WOS:001167008100001},
      doi          = {10.1021/acs.inorgchem.3c04433},
      url          = {https://bib-pubdb1.desy.de/record/603202},
}