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@ARTICLE{Wang:601547,
      author       = {Wang, Yue and Qin, Shanshan and Denisov, Nikita and Kim,
                      Hyesung and Bad'ura, Zdeněk and Sarma, Bidyut Bikash and
                      Schmuki, Patrik},
      title        = {{R}eactive {D}eposition {V}ersus {S}trong {E}lectrostatic
                      {A}dsorption ({SEA}): {A} {K}ey to {H}ighly {A}ctive
                      {S}ingle {A}tom {C}o‐{C}atalysts in {P}hotocatalytic
                      {H}$_2$ {G}eneration},
      journal      = {Advanced materials},
      volume       = {35},
      number       = {32},
      issn         = {0935-9648},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {PUBDB-2024-00256},
      pages        = {2211814},
      year         = {2023},
      abstract     = {In recent years, the use of single atoms (SAs) has become
                      of a rapidly increasing significance in photocatalytic H$_2$
                      generation; here SA noble metals (mainly Pt SAs) can act as
                      highly effective co-catalysts. The classic strategy to
                      decorate oxide semiconductor surfaces with maximally
                      dispersed SAs relies on “strong electrostatic
                      adsorption” (SEA) of suitable noble metal complexes. In
                      the case of TiO$_2$ – the classic benchmark photocatalyst
                      – SEA calls for adsorption of cationic Pt complexes such
                      as [(NH$_3$)$_4$Pt]$^{2+}$ which then are thermally reacted
                      to surface-bound SAs. While SEA is widely used in
                      literature, in the present work it is shown by a direct
                      comparison that reactive attachment based on the reductive
                      anchoring of SAs, e.g., from hexachloroplatinic(IV) acid
                      (H$_2$PtCl$_6$) leads directly to SAs in a configuration
                      with a significantly higher specific activity than SAs
                      deposited with SEA – and this at a significantly lower Pt
                      loading and without any thermal post-deposition treatments.
                      Overall, the work demonstrates that the reactive deposition
                      strategy is superior to the classic SEA concept as it
                      provides a direct electronically well-connected SA-anchoring
                      and thus leads to highly active single-atom sites in
                      photocatalysis.},
      cin          = {DOOR ; HAS-User},
      ddc          = {660},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {6G3 - PETRA III (DESY) (POF4-6G3)},
      pid          = {G:(DE-HGF)POF4-6G3},
      experiment   = {EXP:(DE-H253)P-P65-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {37256585},
      UT           = {WOS:001020077000001},
      doi          = {10.1002/adma.202211814},
      url          = {https://bib-pubdb1.desy.de/record/601547},
}