% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Tikhonov:601075,
      author       = {Tikhonov, Denis and Garg, Diksha and Schnell, Melanie},
      title        = {{I}nverse problems in pump-probe spectroscopy},
      journal      = {Photochem},
      volume       = {4},
      number       = {1},
      issn         = {2673-7256},
      address      = {Basel, Switzerland},
      publisher    = {MDPI},
      reportid     = {PUBDB-2024-00101},
      pages        = {57-110},
      year         = {2024},
      abstract     = {Ultrafast pump-probe spectroscopic studies allow for deep
                      insights into the mechanisms and timescales of photophysical
                      and photochemical processes. Extracting valuable information
                      from these studies, such as reactive intermediates’
                      lifetimes and coherent oscillation frequencies, is an
                      example of the inverse problems of chemical kinetics. This
                      article describes a consistent approach for solving this
                      inverse problem that avoids the common obstacles of simple
                      least-squares fitting that can lead to unreliable results.
                      The presented approach is based on the regularized Markov
                      Chain Monte Carlo sampling for the strongly nonlinear
                      parameters, allowing for a straightforward solution of the
                      ill-posed nonlinear inverse problem. The software to
                      implement the described fitting routine is introduced and
                      the numerical examples of its application are given. We will
                      also touch on criticalexperimental parameters, such as the
                      temporal overlap of pulses and cross-correlation time and
                      their connection to the minimal reachable time resolution.},
      cin          = {FS-SMP},
      ddc          = {540},
      cid          = {I:(DE-H253)FS-SMP-20171124},
      pnm          = {631 - Matter – Dynamics, Mechanisms and Control
                      (POF4-631) / FS-Proposal: F-20191568 (F-20191568)},
      pid          = {G:(DE-HGF)POF4-631 / G:(DE-H253)F-20191568},
      experiment   = {EXP:(DE-H253)F-BL1-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:001268541300001},
      doi          = {10.3390/photochem4010005},
      url          = {https://bib-pubdb1.desy.de/record/601075},
}