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@ARTICLE{Bevione:600018,
author = {Bevione, Matteo and Chiolerio, Alessandro and Tagliabue,
Giulia},
title = {{P}lasmonic {N}anofluids: {E}nhancing {P}hotothermal
{G}radients toward {L}iquid {R}obots},
journal = {ACS applied materials $\&$ interfaces},
volume = {15},
number = {43},
issn = {1944-8244},
address = {Washington, DC},
publisher = {Soc.},
reportid = {PUBDB-2023-07690},
pages = {50106 - 50115},
year = {2023},
abstract = {In situ energy generation in soft, flexible, autonomous
devices is challenging due to the need for highly
stretchable and fault-resistant components. Nanofluids with
pyro-, tribo-, or thermoelectric properties have recently
emerged as promising solutions for realizing liquid-based
energy harvesters. Yet, large thermal gradients are required
for the efficient performance of these systems. In this
work, we show that oil-based plasmonic nanofluids uniquely
combine high photothermal efficiency with strong heat
localization. In particular, we report that oleic acid-based
nanofluids containing TiN nanoclusters (0.3 wt $\%)$ exhibit
$89\%$ photothermal efficiency and can realize thermal
gradients as large as 15.5 K/cm under solar irradiation. We
experimentally and numerically investigate the photothermal
behavior of the nanofluid as a function of solid fraction
concentration and irradiation wavelength, clarifying the
interplay of thermal and optical properties and
demonstrating a dramatic improvement compared with
water-based nanofluids. Overall, these results open
unprecedented opportunities for the development of
liquid-based energy generation systems for soft, stand-alone
devices.},
cin = {DOOR ; HAS-User},
ddc = {600},
cid = {I:(DE-H253)HAS-User-20120731},
pnm = {6G3 - PETRA III (DESY) (POF4-6G3) / FS-Proposal: I-20220029
(I-20220029)},
pid = {G:(DE-HGF)POF4-6G3 / G:(DE-H253)I-20220029},
experiment = {EXP:(DE-H253)P-P03-20150101},
typ = {PUB:(DE-HGF)16},
pubmed = {37853519},
UT = {WOS:001092717600001},
doi = {10.1021/acsami.3c06859},
url = {https://bib-pubdb1.desy.de/record/600018},
}