000599931 001__ 599931
000599931 005__ 20250724132555.0
000599931 0247_ $$2doi$$a10.3390/min13050620
000599931 0247_ $$2datacite_doi$$a10.3204/PUBDB-2023-07620
000599931 0247_ $$2WOS$$aWOS:000998302700001
000599931 0247_ $$2openalex$$aopenalex:W4367627129
000599931 037__ $$aPUBDB-2023-07620
000599931 041__ $$aEnglish
000599931 082__ $$a550
000599931 1001_ $$0P:(DE-H253)PIP1008546$$aPark, Sohyun$$b0$$eCorresponding author
000599931 245__ $$aMechanism for the Combined Li–Na Ionic Conductivity in Sugilite (Fe$_2$Na$_2$K[Li$_3$Si$_{12}$O$_{30}$])-Type Compounds
000599931 260__ $$aBasel$$bMDPI$$c2023
000599931 3367_ $$2DRIVER$$aarticle
000599931 3367_ $$2DataCite$$aOutput Types/Journal article
000599931 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1704980503_1477054
000599931 3367_ $$2BibTeX$$aARTICLE
000599931 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000599931 3367_ $$00$$2EndNote$$aJournal Article
000599931 520__ $$aThis study explains the ionic conductivity in the mineral sugilite (idealized formula: Fe$_2$Na$_2$K[Li$_3$Si$_{12}$O$_{30}$]) by resolving the dynamic disorder of both Li and Na cations using synchrotron X-ray single-crystal diffraction from 298 K to 1023 K. Non-zero anharmonic atomic displacement parameters at Na and Li sites at 1023 K adumbrated long-range charge transport routes for Li and Na cations commonly parallel to the (a–b) plane. Temperature-enhanced diffuse residuals in Fourier maps could unambiguously localize two interstitial sites suitable for Li, as well as three for Na. Each two-dimensional (2D) network of Li and Na interstitials was formed parallel to each other, providing Li and Na hopping pathways. The higher concentration of Na cations hopping in short distances of 2.0962(4)–2.3015(5) Å could be the main reason for the higher bulk conductivity values evaluated by impedance spectra of sugilite in comparison to those of its structural relatives with low Na contents, e.g., the mineral sogdianite ((Zr,Al,Fe)$_2$Na$_{0.36}$K[Li$_3$Si$_{12}$O$_{30}$]). Bond valence sum landscape maps supported the critical role of dynamic disorder of Na$^+$ over densely packed 2D interstitial networks for combined ionic conductivity along with mobile Li+ in sugilite-type compounds.
000599931 536__ $$0G:(DE-HGF)POF4-899$$a899 - ohne Topic (POF4-899)$$cPOF4-899$$fPOF IV$$x0
000599931 588__ $$aDataset connected to CrossRef, Journals: bib-pubdb1.desy.de
000599931 693__ $$0EXP:(DE-H253)D-F1-20150101$$1EXP:(DE-H253)DORISIII-20150101$$6EXP:(DE-H253)D-F1-20150101$$aDORIS III$$fDORIS Beamline F1$$x0
000599931 7001_ $$0P:(DE-H253)PIP1001761$$aPaulmann, Carsten$$b1
000599931 7001_ $$0P:(DE-H253)PIP1008772$$aHoelzel, Markus$$b2
000599931 7001_ $$aHochleitner, Rupert$$b3
000599931 773__ $$0PERI:(DE-600)2655947-X$$a10.3390/min13050620$$gVol. 13, no. 5, p. 620 -$$n5$$p620$$tMinerals$$v13$$x2075-163X$$y2023
000599931 8564_ $$uhttps://bib-pubdb1.desy.de/record/599931/files/minerals-13-00620-v2.pdf$$yOpenAccess
000599931 8564_ $$uhttps://bib-pubdb1.desy.de/record/599931/files/minerals-13-00620-v2.pdf?subformat=pdfa$$xpdfa$$yOpenAccess
000599931 909CO $$ooai:bib-pubdb1.desy.de:599931$$pdnbdelivery$$pdriver$$pVDB$$popen_access$$popenaire
000599931 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1008546$$aExternal Institute$$b0$$kExtern
000599931 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1001761$$aExternal Institute$$b1$$kExtern
000599931 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1008772$$aExternal Institute$$b2$$kExtern
000599931 9131_ $$0G:(DE-HGF)POF4-899$$1G:(DE-HGF)POF4-890$$2G:(DE-HGF)POF4-800$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$aDE-HGF$$bProgrammungebundene Forschung$$lohne Programm$$vohne Topic$$x0
000599931 9141_ $$y2023
000599931 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2023-10-26
000599931 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2023-10-26
000599931 915__ $$0LIC:(DE-HGF)CCBY4$$2HGFVOC$$aCreative Commons Attribution CC BY 4.0
000599931 915__ $$0StatID:(DE-HGF)0600$$2StatID$$aDBCoverage$$bEbsco Academic Search$$d2023-10-26
000599931 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bMINERALS-BASEL : 2022$$d2023-10-26
000599931 915__ $$0StatID:(DE-HGF)0501$$2StatID$$aDBCoverage$$bDOAJ Seal$$d2023-04-12T15:01:16Z
000599931 915__ $$0StatID:(DE-HGF)0500$$2StatID$$aDBCoverage$$bDOAJ$$d2023-04-12T15:01:16Z
000599931 915__ $$0StatID:(DE-HGF)0113$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2023-10-26
000599931 915__ $$0StatID:(DE-HGF)0700$$2StatID$$aFees$$d2023-10-26
000599931 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2023-10-26
000599931 915__ $$0StatID:(DE-HGF)9900$$2StatID$$aIF < 5$$d2023-10-26
000599931 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000599931 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bASC$$d2023-10-26
000599931 915__ $$0StatID:(DE-HGF)0561$$2StatID$$aArticle Processing Charges$$d2023-10-26
000599931 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2023-10-26
000599931 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2023-10-26
000599931 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2023-10-26
000599931 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bDOAJ : Anonymous peer review$$d2023-04-12T15:01:16Z
000599931 9201_ $$0I:(DE-H253)HAS-User-20120731$$kDOOR ; HAS-User$$lDOOR-User$$x0
000599931 980__ $$ajournal
000599931 980__ $$aVDB
000599931 980__ $$aUNRESTRICTED
000599931 980__ $$aI:(DE-H253)HAS-User-20120731
000599931 9801_ $$aFullTexts