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000599051 1001_ $$00000-0001-8274-6882$$aThieu, Nhat Anh$$b0
000599051 245__ $$aSynergistically Stabilizing Zinc Anodes by Molybdenum Dioxide Coating and Tween 80 Electrolyte Additive for High-Performance Aqueous Zinc-Ion Batteries
000599051 260__ $$aWashington, DC$$bSoc.$$c2023
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000599051 520__ $$aRecently, aqueous zinc-ion batteries (ZIBs) have become increasingly attractive as grid-scale energy storage solutions due to their safety, low cost, and environmental friendliness. However, severe dendrite growth, self-corrosion, hydrogen evolution, and irreversible side reactions occurring at Zn anodes often cause poor cyclability of ZIBs. This work develops a synergistic strategy to stabilize the Zn anode by introducing a molybdenum dioxide coating layer on Zn (MoO$_2$@Zn) and Tween 80 as an electrolyte additive. Due to the redox capability and high electrical conductivity of MoO$_2$, the coating layer can not only homogenize the surface electric field but also accommodate the Zn$^{2+}$ concentration field in the vicinity of the Zn anode, thereby regulating Zn$^{2+}$ ion distribution and inhibiting side reactions. MoO$_2$ coating can also significantly enhance surface hydrophilicity to improve the wetting of electrolyte on the Zn electrode. Meanwhile, Tween 80, a surfactant additive, acts as a corrosion inhibitor, preventing Zn corrosion and regulating Zn$^{2+}$ ion migration. Their combination can synergistically work to reduce the desolvation energy of hydrated Zn ions and stabilize the Zn anodes. Therefore, the symmetric cells of MoO$_2$@Zn∥MoO2@Zn with optimal 1 mM Tween 80 additive in 1 M ZnSO$_4$ achieve exceptional cyclability over 6000 h at 1 mA cm$^{-2}$ and stability (>700 h) even at a high current density (5 mA cm$^{-2}$). When coupling with the VO$_2$ cathode, the full cell of MoO$_2$@Zn∥VO$_2$ shows a higher capacity retention (82.4%) compared to Zn∥VO$_2$ (57.3%) after 1000 cycles at 5 A g$^{–1}$. This study suggests a synergistic strategy of combining surface modification and electrolyte engineering to design high-performance ZIBs. 
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000599051 7001_ $$0P:(DE-HGF)0$$aLi, Wei$$b1$$eCorresponding author
000599051 7001_ $$00000-0002-5921-3487$$aChen, Xiujuan$$b2
000599051 7001_ $$00000-0002-4296-9747$$aLi, Qingyuan$$b3
000599051 7001_ $$0P:(DE-H253)PIP1094144$$aWang, Qingsong$$b4
000599051 7001_ $$00009-0001-9751-538X$$aVelayutham, Murugesan$$b5
000599051 7001_ $$00000-0001-7610-8905$$aGrady, Zane M.$$b6
000599051 7001_ $$00009-0008-8978-7757$$aLi, Xuemei$$b7
000599051 7001_ $$00000-0002-8853-225X$$aLi, Wenyuan$$b8
000599051 7001_ $$00000-0001-6187-5546$$aKhramtsov, Valery V.$$b9
000599051 7001_ $$00000-0002-7012-9841$$aReed, David M.$$b10
000599051 7001_ $$0P:(DE-H253)PIP1089381$$aLi, Xiaoling$$b11$$eCorresponding author
000599051 7001_ $$0P:(DE-HGF)0$$aLiu, Xingbo$$b12$$eCorresponding author
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