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100 1 _ |a Akbar, Fariia Iasmin
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245 _ _ |a High-pressure synthesis of dysprosium carbides
260 _ _ |a Lausanne
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520 _ _ |a Chemical reactions between dysprosium and carbon were studied in laser-heated diamond anvil cells at pressures of 19, 55, and 58 GPa and temperatures of ∼2500 K. In situ single-crystal synchrotron X-ray diffraction analysis of the reaction products revealed the formation of novel dysprosium carbides, Dy$_4$C$_3$ and Dy$_3$C$_2$, and dysprosium sesquicarbide Dy$_2$C$_3$ previously known only at ambient conditions. The structure of Dy$_4$C$_3$ was found to be closely related to that of dysprosium sesquicarbide Dy$_2$C$_3$ with the Pu$_2$C$_3$-type structure. Ab initio calculations reproduce well crystal structures of all synthesized phases and predict their compressional behavior in agreement with our experimental data. Our work gives evidence that high-pressure synthesis conditions enrich the chemistry of rare earth metal carbides.
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773 _ _ |a 10.3389/fchem.2023.1210081
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