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@ARTICLE{Sokolov:594794,
author = {Sokolov, Petr S. and Baranov, Andrey N. and Solozhenko,
Vladimir L.},
title = {{C}hemical {P}ressure {E}ffect on the {S}tabilization of
{R}ock-{S}alt {Z}n{O}—{L}i$_{n−2}${M}e{O}$_{n−1}$
{S}olid {S}olutions {S}ynthesized at {H}igh {P}ressure},
journal = {Materials},
volume = {16},
number = {15},
issn = {1996-1944},
address = {Basel},
publisher = {MDPI},
reportid = {PUBDB-2023-05971},
pages = {5336},
year = {2023},
abstract = {Metastable ZnO—Lin$_{n−2}$MeO$_{n−1}$ (Me =
Sc$^{3+}$, Ti$^{4+}$, Ta$^{5+}$) solid solutions with a
rock-salt structure were synthesized through the solid-state
reaction of ZnO with Li$_{n−2}$Me$^{n+}$O$_{n−2}$ (n =
3, 4, 5) complex oxides at 7.7 GPa and 1300–1500 K. In all
investigated systems, single-phase rock-salt solid solutions
can be quenched down to ambient conditions in a wide (up to
80 mol\% ZnO) concentration range. The phase composition,
thermal stability, and thermal expansion of the recovered
rock-salt solid solutions were studied by synchrotron powder
X-ray diffraction. At ambient pressure, these solid
solutions exhibit high thermal stability (up to 1000 K),
with the decomposition temperature and decomposition
products depending on the nature of the multiple charge
cations.},
cin = {DOOR ; HAS-User},
ddc = {600},
cid = {I:(DE-H253)HAS-User-20120731},
pnm = {899 - ohne Topic (POF4-899) / FS-Proposal: I-20070033 EC
(I-20070033-EC) / FS-Proposal: I-20100234 EC
(I-20100234-EC)},
pid = {G:(DE-HGF)POF4-899 / G:(DE-H253)I-20070033-EC /
G:(DE-H253)I-20100234-EC},
experiment = {EXP:(DE-H253)D-B2-20150101 / EXP:(DE-H253)D-F2.1-20150101},
typ = {PUB:(DE-HGF)16},
pubmed = {37570040},
UT = {WOS:001045627900001},
doi = {10.3390/ma16155336},
url = {https://bib-pubdb1.desy.de/record/594794},
}