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000594793 1001_ $$0P:(DE-H253)PIP1011155$$aSokolov, Petr S.$$b0
000594793 245__ $$aPhase stability and thermal expansion of ZnO solid solutions with 3d transition metal oxides synthesized at high pressure
000594793 260__ $$aNew York, NY [u.a.]$$bElsevier$$c2023
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000594793 520__ $$ahase stability and thermal expansion of rock-salt Me$_{1-x}$Zn$_x$O (Me = Ni$^{2+}$, Co$^{2+}$, Fe$^{2+}$, Mn$^{2+}$) solid solutions synthesized at high pressures and high temperatures have been studied by synchrotron X-ray diffraction in a wide (0.1 ≤ x ≤ 0.8) concentration range. At ambient pressure rs-Me$_{1-x}$Zn$_x$O solid solutions were found kinetically stable up to 670–1100 K depending on the composition and type of Me$^{2+}$ cation. Temperature-induced decomposition of the single-phase rock-salt solid solutions lead in most cases to the formation of a mixture of two solid solutions, with cubic and wurtzite structures. Oxidation of the Me$^{2+}$ cation (Co, Mn) by atmospheric oxygen can result in formation of mixed higher oxides of these metals. In all the systems studied, the rock-salt solid solutions show a linear temperature dependence of the thermal expansion, but for the compositions with the highest ZnO content, deviations from the linear dependence are observed.  
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000594793 7001_ $$0P:(DE-H253)PIP1008028$$aBaranov, Andrey N.$$b1
000594793 7001_ $$0P:(DE-H253)PIP1008160$$aSolozhenko, Vladimir L.$$b2$$eCorresponding author
000594793 773__ $$0PERI:(DE-600)1491914-X$$a10.1016/j.jpcs.2023.111437$$gVol. 180, p. 111437 -$$p111437 $$tJournal of physics and chemistry of solids$$v180$$x0022-3697$$y2023
000594793 8564_ $$uhttps://bib-pubdb1.desy.de/record/594793/files/ZnO_SSs.pdf$$yPublished on 2023-09-01. Available in OpenAccess from 2024-09-01.
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