% IMPORTANT: The following is UTF-8 encoded. This means that in the presence % of non-ASCII characters, it will not work with BibTeX 0.99 or older. % Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or % “biber”. @ARTICLE{Hoffmann:588174, author = {Hoffmann, Alexander and Binder, Stephan and Jesser, Anton and Haase, Roxana and Flörke, Ulrich and Gnida, Manuel and Salomone Stagni, Marco and Meyer-Klaucke, Wolfram and Lebsanft, Benjamin and Grünig, Lara Elena and Schneider, Simon and Hashemi, Maryam and Goos, Arne and Wetzel, Alina and Rübhausen, Michael and Herres-Pawlis, Sonja}, title = {{C}atching an {E}ntatic {S}tate-{A} {P}air of {C}opper {C}omplexes}, journal = {Angewandte Chemie / International edition}, volume = {53}, number = {1}, issn = {1433-7851}, address = {Weinheim}, publisher = {Wiley-VCH}, reportid = {PUBDB-2023-04789}, pages = {299 - 304}, year = {2014}, abstract = {The structures of two types of guanidine–quinoline copper complexes have been investigated by single-crystal X-ray crystallography, K-edge X-ray absorption spectroscopy (XAS), resonance Raman and UV/Vis spectroscopy, cyclic voltammetry, and density functional theory (DFT). Independent of the oxidation state, the two structures, which are virtually identical for solids and complexes in solution, resemble each other strongly and are connected by a reversible electron transfer at 0.33 V. By resonant excitation of the two entatic copper complexes, the transition state of the electron transfer is accessible through vibrational modes, which are coupled to metal–ligand charge transfer (MLCT) and ligand–metal charge transfer (LMCT) states.}, cin = {DOOR ; HAS-User / UNI-INF}, ddc = {540}, cid = {I:(DE-H253)HAS-User-20120731 / I:(DE-H253)UNI-INF-20151110}, pnm = {899 - ohne Topic (POF4-899)}, pid = {G:(DE-HGF)POF4-899}, experiment = {EXP:(DE-H253)D-C-20150101 / EXP:(DE-H253)D-E4-20150101 / EXP:(DE-H253)D-X1-20150101}, typ = {PUB:(DE-HGF)16}, pubmed = {pmid:24375742}, UT = {WOS:000328714900047}, doi = {10.1002/anie.201306061}, url = {https://bib-pubdb1.desy.de/record/588174}, }