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@ARTICLE{Sun:586711,
author = {Sun, Wenhao and Schnell, Melanie},
title = {{M}icrowave {T}hree-{W}ave {M}ixing {S}pectroscopy of
{C}hiral {M}olecules in {W}eakly {B}ound {C}omplexes},
journal = {The journal of physical chemistry letters},
volume = {14},
issn = {1948-7185},
address = {Washington, DC},
publisher = {ACS},
reportid = {PUBDB-2023-03970},
pages = {7389 - 7394},
year = {2023},
abstract = {Since the first experimental implementation in 2013,
microwave three-wave mixing has emerged as a robust
spectroscopic approach for analyzing and controlling chiral
molecules in the gas phase. This resonant, coherent, and
nonlinear technique is based on the three-dimensional
light–matter interaction in the electric dipole
approximation, allowing for isomer- and conformer-selective
chiral analysis with high resolution. Here we demonstrate
the utility of microwave three-wave mixing for analyzing a
molecular complex, limonene–H2O, which serves as a
compelling example of addressing its potential to improve
the chiral sensitivity for only weakly polar chiral
molecules. The use of molecular complexes can also extend
the applicability of microwave three-wave mixing to chiral
systems that are not in the C1 point group.},
cin = {FS-SMP},
ddc = {530},
cid = {I:(DE-H253)FS-SMP-20171124},
pnm = {631 - Matter – Dynamics, Mechanisms and Control
(POF4-631) / SFB 1319 B02 - Enantiomerenunterscheidung,
Trennung und Präzisionsuntersuchungen mittels
zugeschnittener Mikrowellenfelder (B02) (389894861)},
pid = {G:(DE-HGF)POF4-631 / G:(GEPRIS)389894861},
experiment = {EXP:(DE-MLZ)NOSPEC-20140101},
typ = {PUB:(DE-HGF)16},
pubmed = {37566689},
UT = {WOS:001048097700001},
doi = {10.1021/acs.jpclett.3c01900},
url = {https://bib-pubdb1.desy.de/record/586711},
}