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@ARTICLE{Ma:585960,
author = {Ma, Xiaoxin and Zheng, Daniel J. and Hou, Shujin and
Mukherjee, Soumya and Khare, Rachit and Gao, Guanhui and Ai,
Qing and Garlyyev, Batyr and Li, Weijin and Koch, Max and
Mink, János and Shao-Horn, Yang and Warnan, Julien and
Bandarenka, Aliaksandr S. and Fischer, Roland A.},
title = {{S}tructure–{A}ctivity {R}elationships in {N}i-
{C}arboxylate-{T}ype {M}etal–{O}rganic {F}rameworks’
{M}etamorphosis for the {O}xygen {E}volution {R}eaction},
journal = {ACS catalysis},
volume = {13},
number = {11},
issn = {2155-5435},
address = {Washington, DC},
publisher = {ACS},
reportid = {PUBDB-2023-03699},
pages = {7587 - 7596},
year = {2023},
note = {Waiting for fulltext},
abstract = {Metal–organic frameworks (MOFs) have been reported to
catalyze the oxygen evolution reaction (OER). Despite the
established links between the pristine MOFs and their
derived metal hydroxide electrocatalysts, several
limitations still preclude understanding of the critical
factors determining the OER performance. Of prime importance
appears the choice of MOF and how its compositions relate to
the catalyst stability and in turn to the reconstruction or
metamorphosis mechanisms into the active species under OER
conditions. An isoreticular series of Ni-carboxylate-type
MOFs [Ni$_2$(OH)$_2$L] was chosen to elucidate the effects
of the carboxylate linker length expansion and modulation of
the linker–linker $π–π$ interactions (L =
1,4-benzodicarboxylate, 2,6-napthalenedicarboxylate,
biphenyl-4,4′-dicarboxylate, and
p-terphenyl-4,4″-dicarboxylate). Degradation and
reconstruction of MOFs were systematically investigated. The
linker controls the transformation of Ni-MOF into distinct
nickel hydroxide phases, and the conversion from
$α$-Ni(OH)$_2$ to $β$-Ni(OH)$_2$, thus correlating the
Ni-MOF composition with the OER activity of the
Ni-MOF-derived metastable nickel hydroxide phase mixture.},
cin = {DOOR ; HAS-User / TUM},
ddc = {540},
cid = {I:(DE-H253)HAS-User-20120731 / I:(DE-588b)36241-4},
pnm = {6G3 - PETRA III (DESY) (POF4-6G3)},
pid = {G:(DE-HGF)POF4-6G3},
experiment = {EXP:(DE-H253)P-P64-20150101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:001006503200001},
doi = {10.1021/acscatal.3c00625},
url = {https://bib-pubdb1.desy.de/record/585960},
}