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@ARTICLE{Raven:490863,
      author       = {Raven, William and Kalf, Irmgard and Paulmann, Carsten and
                      Englert, Ulli},
      title        = {{B}imetallic {O}rganoplatinum({II})‐{A}g({I}) {C}luster
                      {C}ations with {A}g−{P}t {I}nteractions {U}nsupported by
                      {C}onventional {B}ridging {L}igands},
      journal      = {Zeitschrift für anorganische und allgemeine Chemie},
      volume       = {648},
      number       = {12},
      issn         = {0044-2313},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {PUBDB-2022-08084},
      pages        = {e202200019},
      year         = {2022},
      abstract     = {The organoplatinum complex of a primary amine and AgClO$_4$
                      aggregate in methanol to oligonuclear mixed-metal species. A
                      perchlorate salt 3 with the empirical formula
                      C$_{96}$H$_{146}$Ag$_7$Cl$_{13}$N$_{12}$O$_{62}$Pt$_6$ could
                      be isolated and structurally characterized with the help of
                      X-ray diffraction at the DESY synchrotron. The product
                      contains both a penta- and a tetra-nuclear complex cation in
                      which Ag(I) and Pt(II) alternate, held together without any
                      conventional bridge. The cationic species feature short
                      Ag⋅⋅⋅Pt distances between 2.7 and 2.9 Å and
                      contacts longer than 2.4 Å between Ag and C atoms in
                      aromatic rings. In addition to the interactions with Ag(I)
                      cations, Pt(II) is in a square-planar arrangement,
                      coordinated by a chelating and a terminal amine and an aqua
                      ligand. The central Ag(I) in the pentanuclear cation is
                      located on a twofold crystallographic axis and not involved
                      in any obvious coordinative bond; it exclusively shows short
                      contacts to the neighboring Pt(II) ions and the Pt-bonded,
                      formally anionic carbon atoms of the cyclometallated organic
                      ligand. Powder diffraction shows that 3 melts and
                      re-solidifies without decomposition.},
      cin          = {DOOR ; HAS-User / U HH},
      ddc          = {540},
      cid          = {I:(DE-H253)HAS-User-20120731 / $I:(DE-H253)U_HH-20120814$},
      pnm          = {6G3 - PETRA III (DESY) (POF4-6G3)},
      pid          = {G:(DE-HGF)POF4-6G3},
      experiment   = {EXP:(DE-H253)P-P24-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000776741800001},
      doi          = {10.1002/zaac.202200019},
      url          = {https://bib-pubdb1.desy.de/record/490863},
}