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000490863 1001_ $$aRaven, William$$b0
000490863 245__ $$aBimetallic Organoplatinum(II)‐Ag(I) Cluster Cations with Ag−Pt Interactions Unsupported by Conventional Bridging Ligands
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000490863 520__ $$aThe organoplatinum complex of a primary amine and AgClO$_4$ aggregate in methanol to oligonuclear mixed-metal species. A perchlorate salt 3 with the empirical formula C$_{96}$H$_{146}$Ag$_7$Cl$_{13}$N$_{12}$O$_{62}$Pt$_6$ could be isolated and structurally characterized with the help of X-ray diffraction at the DESY synchrotron. The product contains both a penta- and a tetra-nuclear complex cation in which Ag(I) and Pt(II) alternate, held together without any conventional bridge. The cationic species feature short Ag⋅⋅⋅Pt distances between 2.7 and 2.9 Å and contacts longer than 2.4 Å between Ag and C atoms in aromatic rings. In addition to the interactions with Ag(I) cations, Pt(II) is in a square-planar arrangement, coordinated by a chelating and a terminal amine and an aqua ligand. The central Ag(I) in the pentanuclear cation is located on a twofold crystallographic axis and not involved in any obvious coordinative bond; it exclusively shows short contacts to the neighboring Pt(II) ions and the Pt-bonded, formally anionic carbon atoms of the cyclometallated organic ligand. Powder diffraction shows that 3 melts and re-solidifies without decomposition. 
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000490863 7001_ $$aKalf, Irmgard$$b1
000490863 7001_ $$0P:(DE-H253)PIP1001761$$aPaulmann, Carsten$$b2
000490863 7001_ $$0P:(DE-H253)PIP1083053$$aEnglert, Ulli$$b3$$eCorresponding author
000490863 773__ $$0PERI:(DE-600)1481139-X$$a10.1002/zaac.202200019$$gVol. 648, no. 12$$n12$$pe202200019$$tZeitschrift für anorganische und allgemeine Chemie$$v648$$x0044-2313$$y2022
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